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Degradation of atrazine using solar driven fenton-like advanced oxidation processes.
J Environ Sci Health B. 2007 Jan; 42(1):21-6.JE

Abstract

Atrazine (2-chloro-4-ethylamino-6-isopropylamino-s-triazine) was degraded using cobalt-peroximonosulfate (Co/PMS) advanced oxidation process (AOP). Three Co concentrations (0.00, 0.25 and 0.50 mM) and five peroximonosulfate (PMS) concentrations (0, 5, 8, 16 and 32 mM) were tested. Maximum degradation reached was 88% using dark Co/PMS in 126 minutes when 0.25 mM of cobalt and 32 mM of PMS were used. Complete atrazine degradation was achieved when the samples were irradiated by the sun under the same experimental conditions described. Tests for identification of intermediate products allowed identification and quantification of deethylatrazine in both dark and radiated conditions. Kinetic data for both processes was calculated fitting a pseudo-first order reaction rate approach to the experimental data. Having kinetic parameters enabled comparison between both conditions. It was found that the kinetic approach describes data behavior appropriately (R2 > or = 0.95). Pseudo-kinetic constants determined for both Co/PMS processes, show k value of 10(-4) for Co/PMS and a k value of 10(-3) for Co/PMS/ultraviolet (UV). This means, that, with the same Co/PMS concentrations, UV light increases the reaction rate by around one order of magnitude than performing the reaction under dark conditions.

Authors+Show Affiliations

Instituto Mexicano de Tecnologí del Agua, México. ebandala@tlaloc.imta.mxNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't
Research Support, U.S. Gov't, Non-P.H.S.

Language

eng

PubMed ID

17162564

Citation

Bandala, Erick R., et al. "Degradation of Atrazine Using Solar Driven Fenton-like Advanced Oxidation Processes." Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes, vol. 42, no. 1, 2007, pp. 21-6.
Bandala ER, Domínguez Z, Rivas F, et al. Degradation of atrazine using solar driven fenton-like advanced oxidation processes. J Environ Sci Health B. 2007;42(1):21-6.
Bandala, E. R., Domínguez, Z., Rivas, F., & Gelover, S. (2007). Degradation of atrazine using solar driven fenton-like advanced oxidation processes. Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes, 42(1), 21-6.
Bandala ER, et al. Degradation of Atrazine Using Solar Driven Fenton-like Advanced Oxidation Processes. J Environ Sci Health B. 2007;42(1):21-6. PubMed PMID: 17162564.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Degradation of atrazine using solar driven fenton-like advanced oxidation processes. AU - Bandala,Erick R, AU - Domínguez,Zair, AU - Rivas,Fernanda, AU - Gelover,Silvia, PY - 2006/12/13/pubmed PY - 2007/2/28/medline PY - 2006/12/13/entrez SP - 21 EP - 6 JF - Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes JO - J Environ Sci Health B VL - 42 IS - 1 N2 - Atrazine (2-chloro-4-ethylamino-6-isopropylamino-s-triazine) was degraded using cobalt-peroximonosulfate (Co/PMS) advanced oxidation process (AOP). Three Co concentrations (0.00, 0.25 and 0.50 mM) and five peroximonosulfate (PMS) concentrations (0, 5, 8, 16 and 32 mM) were tested. Maximum degradation reached was 88% using dark Co/PMS in 126 minutes when 0.25 mM of cobalt and 32 mM of PMS were used. Complete atrazine degradation was achieved when the samples were irradiated by the sun under the same experimental conditions described. Tests for identification of intermediate products allowed identification and quantification of deethylatrazine in both dark and radiated conditions. Kinetic data for both processes was calculated fitting a pseudo-first order reaction rate approach to the experimental data. Having kinetic parameters enabled comparison between both conditions. It was found that the kinetic approach describes data behavior appropriately (R2 > or = 0.95). Pseudo-kinetic constants determined for both Co/PMS processes, show k value of 10(-4) for Co/PMS and a k value of 10(-3) for Co/PMS/ultraviolet (UV). This means, that, with the same Co/PMS concentrations, UV light increases the reaction rate by around one order of magnitude than performing the reaction under dark conditions. SN - 0360-1234 UR - https://www.unboundmedicine.com/medline/citation/17162564/Degradation_of_atrazine_using_solar_driven_fenton_like_advanced_oxidation_processes_ L2 - https://www.tandfonline.com/doi/full/10.1080/03601230601017965 DB - PRIME DP - Unbound Medicine ER -