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Cationic palladium complex catalyzed highly enantioselective intramolecular addition of arylboronic acids to ketones. A convenient synthesis of optically active cycloalkanols.
J Am Chem Soc. 2006 Dec 27; 128(51):16504-5.JA

Abstract

An efficient and convenient synthesis of optically active cycloalkanols by utilizing the chiral cationic palladium complex as the catalyst was achieved in mild conditions with high yield and high enantioselectivity.

Authors+Show Affiliations

Liu G
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China.
Lu X
No affiliation info available

MeSH

AcetylationAlcoholsBoronic AcidsCatalysisCationsCyclizationKetonesMolecular StructureOptical RotationOrganometallic CompoundsPalladiumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

17177391

Citation

Liu, Guixia, and Xiyan Lu. "Cationic Palladium Complex Catalyzed Highly Enantioselective Intramolecular Addition of Arylboronic Acids to Ketones. a Convenient Synthesis of Optically Active Cycloalkanols." Journal of the American Chemical Society, vol. 128, no. 51, 2006, pp. 16504-5.
Liu G, Lu X. Cationic palladium complex catalyzed highly enantioselective intramolecular addition of arylboronic acids to ketones. A convenient synthesis of optically active cycloalkanols. J Am Chem Soc. 2006;128(51):16504-5.
Liu, G., & Lu, X. (2006). Cationic palladium complex catalyzed highly enantioselective intramolecular addition of arylboronic acids to ketones. A convenient synthesis of optically active cycloalkanols. Journal of the American Chemical Society, 128(51), 16504-5.
Liu G, Lu X. Cationic Palladium Complex Catalyzed Highly Enantioselective Intramolecular Addition of Arylboronic Acids to Ketones. a Convenient Synthesis of Optically Active Cycloalkanols. J Am Chem Soc. 2006 Dec 27;128(51):16504-5. PubMed PMID: 17177391.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Cationic palladium complex catalyzed highly enantioselective intramolecular addition of arylboronic acids to ketones. A convenient synthesis of optically active cycloalkanols. AU - Liu,Guixia, AU - Lu,Xiyan, PY - 2006/12/21/pubmed PY - 2007/2/21/medline PY - 2006/12/21/entrez SP - 16504 EP - 5 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 128 IS - 51 N2 - An efficient and convenient synthesis of optically active cycloalkanols by utilizing the chiral cationic palladium complex as the catalyst was achieved in mild conditions with high yield and high enantioselectivity. SN - 0002-7863 UR - https://www.unboundmedicine.com/medline/citation/17177391/Cationic_palladium_complex_catalyzed_highly_enantioselective_intramolecular_addition_of_arylboronic_acids_to_ketones__A_convenient_synthesis_of_optically_active_cycloalkanols_ L2 - https://doi.org/10.1021/ja0672425 DB - PRIME DP - Unbound Medicine ER -