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Novel synthetic approach toward (+/-)-beta-cuparenone via palladium-catalyzed tandem Heck cyclization of 1-bromo-5-methyl-1-aryl-hexa-1,5-dien-3-ol derivatives.
Org Lett. 2007 Jan 18; 9(2):191-4.OL

Abstract

A novel and convenient synthetic route toward (+/-)-beta-cuparenone and many other sesquiterpene natural product precursors has been developed via palladium-catalyzed tandem Heck cyclization of 1-bromo-5-methyl-1-aryl-hexa-1,5-dien-3-ols. [reaction: see text].

Authors+Show Affiliations

Ray D
Department of Chemistry, Indian Institute of Technology, Kharagpur 721302, India.
Ray JK
No affiliation info available

MeSH

AcetatesAlkadienesCatalysisCyclizationLigandsMolecular StructurePalladiumSesquiterpenesStereoisomerism

Pub Type(s)

Journal Article

Language

eng

PubMed ID

17217262

Citation

Ray, Devalina, and Jayanta K. Ray. "Novel Synthetic Approach Toward (+/-)-beta-cuparenone Via Palladium-catalyzed Tandem Heck Cyclization of 1-bromo-5-methyl-1-aryl-hexa-1,5-dien-3-ol Derivatives." Organic Letters, vol. 9, no. 2, 2007, pp. 191-4.
Ray D, Ray JK. Novel synthetic approach toward (+/-)-beta-cuparenone via palladium-catalyzed tandem Heck cyclization of 1-bromo-5-methyl-1-aryl-hexa-1,5-dien-3-ol derivatives. Org Lett. 2007;9(2):191-4.
Ray, D., & Ray, J. K. (2007). Novel synthetic approach toward (+/-)-beta-cuparenone via palladium-catalyzed tandem Heck cyclization of 1-bromo-5-methyl-1-aryl-hexa-1,5-dien-3-ol derivatives. Organic Letters, 9(2), 191-4.
Ray D, Ray JK. Novel Synthetic Approach Toward (+/-)-beta-cuparenone Via Palladium-catalyzed Tandem Heck Cyclization of 1-bromo-5-methyl-1-aryl-hexa-1,5-dien-3-ol Derivatives. Org Lett. 2007 Jan 18;9(2):191-4. PubMed PMID: 17217262.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Novel synthetic approach toward (+/-)-beta-cuparenone via palladium-catalyzed tandem Heck cyclization of 1-bromo-5-methyl-1-aryl-hexa-1,5-dien-3-ol derivatives. AU - Ray,Devalina, AU - Ray,Jayanta K, PY - 2007/1/16/pubmed PY - 2007/3/21/medline PY - 2007/1/16/entrez SP - 191 EP - 4 JF - Organic letters JO - Org Lett VL - 9 IS - 2 N2 - A novel and convenient synthetic route toward (+/-)-beta-cuparenone and many other sesquiterpene natural product precursors has been developed via palladium-catalyzed tandem Heck cyclization of 1-bromo-5-methyl-1-aryl-hexa-1,5-dien-3-ols. [reaction: see text]. SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/17217262/Novel_synthetic_approach_toward__+/___beta_cuparenone_via_palladium_catalyzed_tandem_Heck_cyclization_of_1_bromo_5_methyl_1_aryl_hexa_15_dien_3_ol_derivatives_ L2 - https://doi.org/10.1021/ol062418t DB - PRIME DP - Unbound Medicine ER -