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3-[(3-Dehydroabietamidopropyl)dimethylammonio]-1-propane-sulfonate as a new type of chiral surfactant for enantiomer separation in micellar electrokinetic chromatography.
J Chromatogr A. 2007 Mar 23; 1145(1-2):246-9.JC

Abstract

A new type of chiral surfactant, 3-[(3-dehydroabietamidopropyl) dimethylammonio]-1-propanesulfonate (DHAMAP) has been synthesized. The ability of this compound to perform chiral separation of D/L-amino acids derivatized with naphthalene-2, 3-dicarboxaldehyde (NDA-D/L-amino acids) has been investigated by capillary electrophoresis (CE). Enantiomeric separation of NDA-D/L-amino acids was achieved with a running buffer consisting of 50 mM borate (pH 9.75) and 25 mM DHADMP. Under the conditions selected, 6 pairs of tested amino acids enantiomers including NDA-D/L-tryptophan, NDA-D/L-phenylalanine, D/L-D/L-kynurenine, NDA-D/L-beta-phenylalanine, NDA-D/L-4-methylphenylalanine and NDA-D/L-arginine were well resolved. The resolution values were in the range of 1.56-5.40.

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Authors+Show Affiliations

Zhao S
College of Chemistry and Chemical Engineering, Guangxi Nomal University, Guilin 541004, China. zhaoshulin001@163.com
Wang H
No affiliation info available
Pan Y
No affiliation info available
He M
No affiliation info available
Zhao Z
No affiliation info available

MeSH

AlkanesulfonatesChromatography, Micellar Electrokinetic CapillaryElectrophoresis, CapillaryMolecular StructureReproducibility of ResultsStereoisomerismSurface-Active Agents

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

17307190

Citation

Zhao, Shulin, et al. "3-[(3-Dehydroabietamidopropyl)dimethylammonio]-1-propane-sulfonate as a New Type of Chiral Surfactant for Enantiomer Separation in Micellar Electrokinetic Chromatography." Journal of Chromatography. A, vol. 1145, no. 1-2, 2007, pp. 246-9.
Zhao S, Wang H, Pan Y, et al. 3-[(3-Dehydroabietamidopropyl)dimethylammonio]-1-propane-sulfonate as a new type of chiral surfactant for enantiomer separation in micellar electrokinetic chromatography. J Chromatogr A. 2007;1145(1-2):246-9.
Zhao, S., Wang, H., Pan, Y., He, M., & Zhao, Z. (2007). 3-[(3-Dehydroabietamidopropyl)dimethylammonio]-1-propane-sulfonate as a new type of chiral surfactant for enantiomer separation in micellar electrokinetic chromatography. Journal of Chromatography. A, 1145(1-2), 246-9.
Zhao S, et al. 3-[(3-Dehydroabietamidopropyl)dimethylammonio]-1-propane-sulfonate as a New Type of Chiral Surfactant for Enantiomer Separation in Micellar Electrokinetic Chromatography. J Chromatogr A. 2007 Mar 23;1145(1-2):246-9. PubMed PMID: 17307190.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - 3-[(3-Dehydroabietamidopropyl)dimethylammonio]-1-propane-sulfonate as a new type of chiral surfactant for enantiomer separation in micellar electrokinetic chromatography. AU - Zhao,Shulin, AU - Wang,Hengshan, AU - Pan,Yingming, AU - He,Min, AU - Zhao,Zhicai, Y1 - 2007/02/09/ PY - 2006/08/18/received PY - 2007/01/14/revised PY - 2007/01/24/accepted PY - 2007/2/20/pubmed PY - 2007/5/22/medline PY - 2007/2/20/entrez SP - 246 EP - 9 JF - Journal of chromatography. A JO - J Chromatogr A VL - 1145 IS - 1-2 N2 - A new type of chiral surfactant, 3-[(3-dehydroabietamidopropyl) dimethylammonio]-1-propanesulfonate (DHAMAP) has been synthesized. The ability of this compound to perform chiral separation of D/L-amino acids derivatized with naphthalene-2, 3-dicarboxaldehyde (NDA-D/L-amino acids) has been investigated by capillary electrophoresis (CE). Enantiomeric separation of NDA-D/L-amino acids was achieved with a running buffer consisting of 50 mM borate (pH 9.75) and 25 mM DHADMP. Under the conditions selected, 6 pairs of tested amino acids enantiomers including NDA-D/L-tryptophan, NDA-D/L-phenylalanine, D/L-D/L-kynurenine, NDA-D/L-beta-phenylalanine, NDA-D/L-4-methylphenylalanine and NDA-D/L-arginine were well resolved. The resolution values were in the range of 1.56-5.40. SN - 0021-9673 UR - https://www.unboundmedicine.com/medline/citation/17307190/3_[_3_Dehydroabietamidopropyl_dimethylammonio]_1_propane_sulfonate_as_a_new_type_of_chiral_surfactant_for_enantiomer_separation_in_micellar_electrokinetic_chromatography_ L2 - https://linkinghub.elsevier.com/retrieve/pii/S0021-9673(07)00168-9 DB - PRIME DP - Unbound Medicine ER -