Highly enantioselective water-compatible organocatalyst for Michael reaction of ketones to nitroolefins.Org Lett. 2007 Mar 15; 9(6):1117-9.OL
Abstract
A chiral diamine was found to catalyze enantioselective addition of ketones to nitroolefins in aqueous/saline/organic media. The products were obtained with excellent diastereoselectivities (syn/anti = 99:1) and enantioselectivities up to 99%. The reaction could be facilitated using a mild acid. [reaction: see text]
Pub Type(s)
Journal Article
Language
eng
PubMed ID
17316013
Citation
Vishnumaya, , and Vinod K. Singh. "Highly Enantioselective Water-compatible Organocatalyst for Michael Reaction of Ketones to Nitroolefins." Organic Letters, vol. 9, no. 6, 2007, pp. 1117-9.
Vishnumaya , Singh VK. Highly enantioselective water-compatible organocatalyst for Michael reaction of ketones to nitroolefins. Org Lett. 2007;9(6):1117-9.
Vishnumaya, ., & Singh, V. K. (2007). Highly enantioselective water-compatible organocatalyst for Michael reaction of ketones to nitroolefins. Organic Letters, 9(6), 1117-9.
Vishnumaya , Singh VK. Highly Enantioselective Water-compatible Organocatalyst for Michael Reaction of Ketones to Nitroolefins. Org Lett. 2007 Mar 15;9(6):1117-9. PubMed PMID: 17316013.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR
T1 - Highly enantioselective water-compatible organocatalyst for Michael reaction of ketones to nitroolefins.
AU - Vishnumaya,,
AU - Singh,Vinod K,
Y1 - 2007/02/23/
PY - 2007/2/24/pubmed
PY - 2007/2/24/medline
PY - 2007/2/24/entrez
SP - 1117
EP - 9
JF - Organic letters
JO - Org Lett
VL - 9
IS - 6
N2 - A chiral diamine was found to catalyze enantioselective addition of ketones to nitroolefins in aqueous/saline/organic media. The products were obtained with excellent diastereoselectivities (syn/anti = 99:1) and enantioselectivities up to 99%. The reaction could be facilitated using a mild acid. [reaction: see text]
SN - 1523-7060
UR - https://www.unboundmedicine.com/medline/citation/17316013/Highly_enantioselective_water_compatible_organocatalyst_for_Michael_reaction_of_ketones_to_nitroolefins_
L2 - https://doi.org/10.1021/ol070082x
DB - PRIME
DP - Unbound Medicine
ER -
