Transition metal catalyzed carbon-silicon bond forming reactions using chlorosilanes promoted by Grignard reagents.
Chem Rec. 2007; 7(1):57-67.CR

Abstract

New catalytic C--Si bond-forming reactions using chlorosilanes are described. These reactions proceed efficiently under mild conditions by the combined use of Grignard reagents and transition metal catalysts, such as Ti, Zr, Ni, and Pd. It is proposed that ate complex intermediates formed by the reaction of transition metals with Grignard reagents play important roles as the active catalytic species. The present study demonstrates the practical use of chlorosilanes in transition metal catalyzed silylation reactions providing convenient methods for allyl- or vinylsilane synthesis. The reaction pathways of these transformations as well as the scope and limitations are discussed.

Authors+Show Affiliations

Terao J

Department of Applied Chemistry & Center for Atomic and Molecular Technologies Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.

Kambe N

No affiliation info available

Pub Type(s)

Journal Article

Language

eng

PubMed ID

17318829

Citation

Terao, Jun, and Nobuaki Kambe. "Transition Metal Catalyzed Carbon-silicon Bond Forming Reactions Using Chlorosilanes Promoted By Grignard Reagents." Chemical Record (New York, N.Y.), vol. 7, no. 1, 2007, pp. 57-67.

Terao J, Kambe N. Transition metal catalyzed carbon-silicon bond forming reactions using chlorosilanes promoted by Grignard reagents. Chem Rec. 2007;7(1):57-67.

Terao, J., & Kambe, N. (2007). Transition metal catalyzed carbon-silicon bond forming reactions using chlorosilanes promoted by Grignard reagents. Chemical Record (New York, N.Y.), 7(1), 57-67.

Terao J, Kambe N. Transition Metal Catalyzed Carbon-silicon Bond Forming Reactions Using Chlorosilanes Promoted By Grignard Reagents. Chem Rec. 2007;7(1):57-67. PubMed PMID: 17318829.

* Article titles in AMA citation format should be in sentence-case

TY - JOUR T1 - Transition metal catalyzed carbon-silicon bond forming reactions using chlorosilanes promoted by Grignard reagents. AU - Terao,Jun, AU - Kambe,Nobuaki, PY - 2007/2/24/pubmed PY - 2007/2/24/medline PY - 2007/2/24/entrez SP - 57 EP - 67 JF - Chemical record (New York, N.Y.) JO - Chem Rec VL - 7 IS - 1 N2 - New catalytic C--Si bond-forming reactions using chlorosilanes are described. These reactions proceed efficiently under mild conditions by the combined use of Grignard reagents and transition metal catalysts, such as Ti, Zr, Ni, and Pd. It is proposed that ate complex intermediates formed by the reaction of transition metals with Grignard reagents play important roles as the active catalytic species. The present study demonstrates the practical use of chlorosilanes in transition metal catalyzed silylation reactions providing convenient methods for allyl- or vinylsilane synthesis. The reaction pathways of these transformations as well as the scope and limitations are discussed. SN - 1527-8999 UR - https://www.unboundmedicine.com/medline/citation/17318829/Transition_metal_catalyzed_carbon_silicon_bond_forming_reactions_using_chlorosilanes_promoted_by_Grignard_reagents_ L2 - https://doi.org/10.1002/tcr.20101 DB - PRIME DP - Unbound Medicine ER -

Tags

Transition metal catalyzed carbon-silicon bond forming reactions using chlorosilanes promoted by Grignard reagents.Chem Rec. 2007; 7(1):57-67.CR