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Regiospecific organocatalytic asymmetric aldol reaction of methyl ketones and alpha,beta-unsaturated trifluoromethyl ketones.
Org Lett. 2007 Mar 29; 9(7):1343-5.OL

Abstract

[structure: see text]. The aldol reaction of methyl ketones and alpha,beta-unsaturated trifluoromethyl ketones occurred under mild conditions with the combination of proline-derived N-sulfonylamide and trifluoroacetic acid as the catalyst to give the corresponding unsaturated alpha-trifluoromethyl tertiary alcohols in high yields with good enatioselectivities.

Authors+Show Affiliations

Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, China.No affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

17348668

Citation

Wang, Xiao-Jin, et al. "Regiospecific Organocatalytic Asymmetric Aldol Reaction of Methyl Ketones and Alpha,beta-unsaturated Trifluoromethyl Ketones." Organic Letters, vol. 9, no. 7, 2007, pp. 1343-5.
Wang XJ, Zhao Y, Liu JT. Regiospecific organocatalytic asymmetric aldol reaction of methyl ketones and alpha,beta-unsaturated trifluoromethyl ketones. Org Lett. 2007;9(7):1343-5.
Wang, X. J., Zhao, Y., & Liu, J. T. (2007). Regiospecific organocatalytic asymmetric aldol reaction of methyl ketones and alpha,beta-unsaturated trifluoromethyl ketones. Organic Letters, 9(7), 1343-5.
Wang XJ, Zhao Y, Liu JT. Regiospecific Organocatalytic Asymmetric Aldol Reaction of Methyl Ketones and Alpha,beta-unsaturated Trifluoromethyl Ketones. Org Lett. 2007 Mar 29;9(7):1343-5. PubMed PMID: 17348668.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Regiospecific organocatalytic asymmetric aldol reaction of methyl ketones and alpha,beta-unsaturated trifluoromethyl ketones. AU - Wang,Xiao-Jin, AU - Zhao,Yan, AU - Liu,Jin-Tao, Y1 - 2007/03/10/ PY - 2007/3/14/pubmed PY - 2007/5/16/medline PY - 2007/3/14/entrez SP - 1343 EP - 5 JF - Organic letters JO - Org Lett VL - 9 IS - 7 N2 - [structure: see text]. The aldol reaction of methyl ketones and alpha,beta-unsaturated trifluoromethyl ketones occurred under mild conditions with the combination of proline-derived N-sulfonylamide and trifluoroacetic acid as the catalyst to give the corresponding unsaturated alpha-trifluoromethyl tertiary alcohols in high yields with good enatioselectivities. SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/17348668/Regiospecific_organocatalytic_asymmetric_aldol_reaction_of_methyl_ketones_and_alphabeta_unsaturated_trifluoromethyl_ketones_ L2 - https://doi.org/10.1021/ol070217z DB - PRIME DP - Unbound Medicine ER -