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Comparison of disinfection byproduct formation from chlorine and alternative disinfectants.
Water Res. 2007 Apr; 41(8):1667-78.WR

Abstract

Seven diverse natural waters were collected and treated in the laboratory under five oxidation scenarios (chlorine, chloramine, both with and without preozonation, and chlorine dioxide). The impact of these disinfectants on the formation of disinfection byproducts was investigated. Results showed that preozonation decreased the formation of trihalomethanes (THMs), haloacetic acids (HAAs) and total organic halogen (TOX) for most waters during postchlorination. A net increase in THMs, HAAs and TOX was observed for a water of low humic content. Either decreases or increases were observed in dihaloacetic acids and unknown TOX (UTOX) as a result of preozonation when used with chloramination. Chloramines and chlorine dioxide produced a higher percentage of UTOX than free chlorine. They also formed more iodoform and total organic iodine (TOI) than free chlorine in the presence of iodide. Free chlorine produced a much higher level of total organic chlorine (TOCl) and bromine (TOBr) than chloramines and chlorine dioxide in the presence of bromide.

Authors+Show Affiliations

Department of Civil and Environmental Engineering, University of Massachusetts, Amherst, MA 01003, USA.No affiliation info available

Pub Type(s)

Comparative Study
Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

17360020

Citation

Hua, Guanghui, and David A. Reckhow. "Comparison of Disinfection Byproduct Formation From Chlorine and Alternative Disinfectants." Water Research, vol. 41, no. 8, 2007, pp. 1667-78.
Hua G, Reckhow DA. Comparison of disinfection byproduct formation from chlorine and alternative disinfectants. Water Res. 2007;41(8):1667-78.
Hua, G., & Reckhow, D. A. (2007). Comparison of disinfection byproduct formation from chlorine and alternative disinfectants. Water Research, 41(8), 1667-78.
Hua G, Reckhow DA. Comparison of Disinfection Byproduct Formation From Chlorine and Alternative Disinfectants. Water Res. 2007;41(8):1667-78. PubMed PMID: 17360020.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Comparison of disinfection byproduct formation from chlorine and alternative disinfectants. AU - Hua,Guanghui, AU - Reckhow,David A, Y1 - 2007/03/13/ PY - 2006/09/14/received PY - 2007/01/22/revised PY - 2007/01/24/accepted PY - 2007/3/16/pubmed PY - 2007/6/5/medline PY - 2007/3/16/entrez SP - 1667 EP - 78 JF - Water research JO - Water Res VL - 41 IS - 8 N2 - Seven diverse natural waters were collected and treated in the laboratory under five oxidation scenarios (chlorine, chloramine, both with and without preozonation, and chlorine dioxide). The impact of these disinfectants on the formation of disinfection byproducts was investigated. Results showed that preozonation decreased the formation of trihalomethanes (THMs), haloacetic acids (HAAs) and total organic halogen (TOX) for most waters during postchlorination. A net increase in THMs, HAAs and TOX was observed for a water of low humic content. Either decreases or increases were observed in dihaloacetic acids and unknown TOX (UTOX) as a result of preozonation when used with chloramination. Chloramines and chlorine dioxide produced a higher percentage of UTOX than free chlorine. They also formed more iodoform and total organic iodine (TOI) than free chlorine in the presence of iodide. Free chlorine produced a much higher level of total organic chlorine (TOCl) and bromine (TOBr) than chloramines and chlorine dioxide in the presence of bromide. SN - 0043-1354 UR - https://www.unboundmedicine.com/medline/citation/17360020/Comparison_of_disinfection_byproduct_formation_from_chlorine_and_alternative_disinfectants_ L2 - https://linkinghub.elsevier.com/retrieve/pii/S0043-1354(07)00061-9 DB - PRIME DP - Unbound Medicine ER -