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Catalytic enantioselective Friedel-Crafts alkylations of indoles with alpha'-phosphoric enones.
Org Lett. 2007 Jun 07; 9(12):2281-4.OL

Abstract

The C2-symmetric bis(oxazoline) copper(II) complex proves to be an excellent catalyst in the Friedel-Crafts alkylation of indoles with alpha'-phosphoric enones. The enantioselectivities of this reaction are obtained in up to 98% ee.

Authors+Show Affiliations

Yang H
Center for Molecular Design & Synthesis and Department of Chemistry, School of Molecular Science, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Korea.
Hong YT
No affiliation info available
Kim S
No affiliation info available

MeSH

AlkylationCatalysisCopperIndolesKetonesMolecular StructureOrganometallic CompoundsOrganophosphonatesStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

17497795

Citation

Yang, Hyeyeon, et al. "Catalytic Enantioselective Friedel-Crafts Alkylations of Indoles With Alpha'-phosphoric Enones." Organic Letters, vol. 9, no. 12, 2007, pp. 2281-4.
Yang H, Hong YT, Kim S. Catalytic enantioselective Friedel-Crafts alkylations of indoles with alpha'-phosphoric enones. Org Lett. 2007;9(12):2281-4.
Yang, H., Hong, Y. T., & Kim, S. (2007). Catalytic enantioselective Friedel-Crafts alkylations of indoles with alpha'-phosphoric enones. Organic Letters, 9(12), 2281-4.
Yang H, Hong YT, Kim S. Catalytic Enantioselective Friedel-Crafts Alkylations of Indoles With Alpha'-phosphoric Enones. Org Lett. 2007 Jun 7;9(12):2281-4. PubMed PMID: 17497795.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Catalytic enantioselective Friedel-Crafts alkylations of indoles with alpha'-phosphoric enones. AU - Yang,Hyeyeon, AU - Hong,Young-Taek, AU - Kim,Sunggak, Y1 - 2007/05/11/ PY - 2007/5/15/pubmed PY - 2007/8/19/medline PY - 2007/5/15/entrez SP - 2281 EP - 4 JF - Organic letters JO - Org Lett VL - 9 IS - 12 N2 - The C2-symmetric bis(oxazoline) copper(II) complex proves to be an excellent catalyst in the Friedel-Crafts alkylation of indoles with alpha'-phosphoric enones. The enantioselectivities of this reaction are obtained in up to 98% ee. SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/17497795/Catalytic_enantioselective_Friedel_Crafts_alkylations_of_indoles_with_alpha'_phosphoric_enones_ L2 - https://doi.org/10.1021/ol070548b DB - PRIME DP - Unbound Medicine ER -