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Identification and quantitation of pyrethroid pesticide residues in vegetables by solid-phase extraction and liquid chromatography/electrospray ionization ion trap mass spectrometry.
Rapid Commun Mass Spectrom. 2007; 21(12):1848-54.RC

Abstract

A quantitative method consisting of solid-phase extraction (SPE) followed by liquid chromatography/electrospray ionization ion trap mass spectrometry (LC/ESI-ITMS) analysis was developed for the identification and quantitation of ten pyrethroid pesticides commonly used in vegetables. The best HPLC separation was achieved using a gradient program of methanol/water mixture. For the vegetable samples, an SPE procedure to clean up the matrices was carried out prior to LC/MS analysis. Under the optimum conditions, the limits of quantification of the pyrethroid pesticides (tetramethrin, allethrin, fenpropathrin, lambda-cyhalothrin, cypermethrin, deltamethrin, fenvalerate, bioresmethrin, permethrin and bifenthrin) ranged from 0.03 to 0.1 mg kg-1 with relative standard deviations<20%, and the mean recoveries ranged from 69.5 to 102.5%. The proposed method has been successfully applied to the determination of pyrethroids in six vegetables with satisfactory results.

Authors+Show Affiliations

Chen T
Ministry of Education Key Laboratory of Analysis and Detection Technology for Food Safety, Department of Chemistry, Fuzhou University, Fuzhou, Fujian, 350002, China.
Chen G
No affiliation info available

MeSH

Chromatography, High Pressure LiquidFood ContaminationPesticide ResiduesPyrethrinsReproducibility of ResultsSensitivity and SpecificitySpectrometry, Mass, Electrospray IonizationVegetables

Pub Type(s)

Evaluation Study
Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

17510928

Citation

Chen, Tianwen, and Guonan Chen. "Identification and Quantitation of Pyrethroid Pesticide Residues in Vegetables By Solid-phase Extraction and Liquid Chromatography/electrospray Ionization Ion Trap Mass Spectrometry." Rapid Communications in Mass Spectrometry : RCM, vol. 21, no. 12, 2007, pp. 1848-54.
Chen T, Chen G. Identification and quantitation of pyrethroid pesticide residues in vegetables by solid-phase extraction and liquid chromatography/electrospray ionization ion trap mass spectrometry. Rapid Commun Mass Spectrom. 2007;21(12):1848-54.
Chen, T., & Chen, G. (2007). Identification and quantitation of pyrethroid pesticide residues in vegetables by solid-phase extraction and liquid chromatography/electrospray ionization ion trap mass spectrometry. Rapid Communications in Mass Spectrometry : RCM, 21(12), 1848-54.
Chen T, Chen G. Identification and Quantitation of Pyrethroid Pesticide Residues in Vegetables By Solid-phase Extraction and Liquid Chromatography/electrospray Ionization Ion Trap Mass Spectrometry. Rapid Commun Mass Spectrom. 2007;21(12):1848-54. PubMed PMID: 17510928.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Identification and quantitation of pyrethroid pesticide residues in vegetables by solid-phase extraction and liquid chromatography/electrospray ionization ion trap mass spectrometry. AU - Chen,Tianwen, AU - Chen,Guonan, PY - 2007/5/19/pubmed PY - 2007/8/8/medline PY - 2007/5/19/entrez SP - 1848 EP - 54 JF - Rapid communications in mass spectrometry : RCM JO - Rapid Commun Mass Spectrom VL - 21 IS - 12 N2 - A quantitative method consisting of solid-phase extraction (SPE) followed by liquid chromatography/electrospray ionization ion trap mass spectrometry (LC/ESI-ITMS) analysis was developed for the identification and quantitation of ten pyrethroid pesticides commonly used in vegetables. The best HPLC separation was achieved using a gradient program of methanol/water mixture. For the vegetable samples, an SPE procedure to clean up the matrices was carried out prior to LC/MS analysis. Under the optimum conditions, the limits of quantification of the pyrethroid pesticides (tetramethrin, allethrin, fenpropathrin, lambda-cyhalothrin, cypermethrin, deltamethrin, fenvalerate, bioresmethrin, permethrin and bifenthrin) ranged from 0.03 to 0.1 mg kg-1 with relative standard deviations<20%, and the mean recoveries ranged from 69.5 to 102.5%. The proposed method has been successfully applied to the determination of pyrethroids in six vegetables with satisfactory results. SN - 0951-4198 UR - https://www.unboundmedicine.com/medline/citation/17510928/Identification_and_quantitation_of_pyrethroid_pesticide_residues_in_vegetables_by_solid_phase_extraction_and_liquid_chromatography/electrospray_ionization_ion_trap_mass_spectrometry_ L2 - https://doi.org/10.1002/rcm.3027 DB - PRIME DP - Unbound Medicine ER -

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