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Ir-catalyzed regio- and enantioselective decarboxylative allylic alkylations.
Org Lett. 2007 Oct 11; 9(21):4339-41.OL

Abstract

[Ir(COD)Cl]2/phosphoramidite ligand 1a was found to be an efficient catalytic system for the highly regio- and enantioselective decarboxylative alkylation of gamma-substituted allyl beta-ketocarboxylates, affording the branched products with up to >99/1 branched-linear ratio and 96% ee.

Authors+Show Affiliations

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China.No affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article

Language

eng

PubMed ID

17854201

Citation

He, Hu, et al. "Ir-catalyzed Regio- and Enantioselective Decarboxylative Allylic Alkylations." Organic Letters, vol. 9, no. 21, 2007, pp. 4339-41.
He H, Zheng XJ, Li Y, et al. Ir-catalyzed regio- and enantioselective decarboxylative allylic alkylations. Org Lett. 2007;9(21):4339-41.
He, H., Zheng, X. J., Li, Y., Dai, L. X., & You, S. L. (2007). Ir-catalyzed regio- and enantioselective decarboxylative allylic alkylations. Organic Letters, 9(21), 4339-41.
He H, et al. Ir-catalyzed Regio- and Enantioselective Decarboxylative Allylic Alkylations. Org Lett. 2007 Oct 11;9(21):4339-41. PubMed PMID: 17854201.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Ir-catalyzed regio- and enantioselective decarboxylative allylic alkylations. AU - He,Hu, AU - Zheng,Xiao-Jian, AU - Li,Yi, AU - Dai,Li-Xin, AU - You,Shu-Li, Y1 - 2007/09/14/ PY - 2007/9/15/pubmed PY - 2007/9/15/medline PY - 2007/9/15/entrez SP - 4339 EP - 41 JF - Organic letters JO - Org Lett VL - 9 IS - 21 N2 - [Ir(COD)Cl]2/phosphoramidite ligand 1a was found to be an efficient catalytic system for the highly regio- and enantioselective decarboxylative alkylation of gamma-substituted allyl beta-ketocarboxylates, affording the branched products with up to >99/1 branched-linear ratio and 96% ee. SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/17854201/Ir_catalyzed_regio__and_enantioselective_decarboxylative_allylic_alkylations_ DB - PRIME DP - Unbound Medicine ER -
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