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Use of Rhizopus oligosporus produced from food processing wastewater as a biosorbent for Cu(II) ions removal from the aqueous solutions.
Bioresour Technol. 2008 Jul; 99(11):4943-8.BT

Abstract

Dried biomass of Rhizopus oligosporus produced from food processing wastewater was used as an adsorbent for copper ions in water. The adsorption process was carried out in a batch process and the effects of contact time (1-48 h), initial pH (2.0-6.0), initial metal ion concentration (20-100 mg L(-1)) and temperature (20-38 degrees C) on the adsorption were investigated. Experimental results showed that the maximum adsorption capacity was achieved at pH 5.0 and adsorbed Cu(II) ion concentration was increased with increasing initial metal concentration and contact time. The isothermal data could be described well by the Langmuir equations and monolayer capacity had a mean value of 79.37 mg g(-1). A pseudo-second order reaction model provided the best description of the data with a correlation coefficient 0.99 for different initial metal concentrations. Thermodynamic parameters indicated that biosorption of Cu(II) on R. oligosporus dried biomass was exothermic and spontaneous. To observe the copper pellets on the biosorbent surface after biosorption SEM was used and copper was characterized by EDX. The results of FTIR analyses indicated that amide I and hydroxyl groups of adsorbent played important role in binding Cu(II).

Authors+Show Affiliations

Department of Environmental Engineering, Engineering Faculty, Mersin University, 33360, Turkey. ozsoyhd@mersin.edu.trNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

17964150

Citation

Ozsoy, H Duygu, et al. "Use of Rhizopus Oligosporus Produced From Food Processing Wastewater as a Biosorbent for Cu(II) Ions Removal From the Aqueous Solutions." Bioresource Technology, vol. 99, no. 11, 2008, pp. 4943-8.
Ozsoy HD, Kumbur H, Saha B, et al. Use of Rhizopus oligosporus produced from food processing wastewater as a biosorbent for Cu(II) ions removal from the aqueous solutions. Bioresour Technol. 2008;99(11):4943-8.
Ozsoy, H. D., Kumbur, H., Saha, B., & van Leeuwen, J. H. (2008). Use of Rhizopus oligosporus produced from food processing wastewater as a biosorbent for Cu(II) ions removal from the aqueous solutions. Bioresource Technology, 99(11), 4943-8.
Ozsoy HD, et al. Use of Rhizopus Oligosporus Produced From Food Processing Wastewater as a Biosorbent for Cu(II) Ions Removal From the Aqueous Solutions. Bioresour Technol. 2008;99(11):4943-8. PubMed PMID: 17964150.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Use of Rhizopus oligosporus produced from food processing wastewater as a biosorbent for Cu(II) ions removal from the aqueous solutions. AU - Ozsoy,H Duygu, AU - Kumbur,Halil, AU - Saha,Basudeb, AU - van Leeuwen,J Hans, Y1 - 2007/10/25/ PY - 2007/01/16/received PY - 2007/09/05/revised PY - 2007/09/10/accepted PY - 2007/10/30/pubmed PY - 2008/8/5/medline PY - 2007/10/30/entrez SP - 4943 EP - 8 JF - Bioresource technology JO - Bioresour Technol VL - 99 IS - 11 N2 - Dried biomass of Rhizopus oligosporus produced from food processing wastewater was used as an adsorbent for copper ions in water. The adsorption process was carried out in a batch process and the effects of contact time (1-48 h), initial pH (2.0-6.0), initial metal ion concentration (20-100 mg L(-1)) and temperature (20-38 degrees C) on the adsorption were investigated. Experimental results showed that the maximum adsorption capacity was achieved at pH 5.0 and adsorbed Cu(II) ion concentration was increased with increasing initial metal concentration and contact time. The isothermal data could be described well by the Langmuir equations and monolayer capacity had a mean value of 79.37 mg g(-1). A pseudo-second order reaction model provided the best description of the data with a correlation coefficient 0.99 for different initial metal concentrations. Thermodynamic parameters indicated that biosorption of Cu(II) on R. oligosporus dried biomass was exothermic and spontaneous. To observe the copper pellets on the biosorbent surface after biosorption SEM was used and copper was characterized by EDX. The results of FTIR analyses indicated that amide I and hydroxyl groups of adsorbent played important role in binding Cu(II). SN - 0960-8524 UR - https://www.unboundmedicine.com/medline/citation/17964150/Use_of_Rhizopus_oligosporus_produced_from_food_processing_wastewater_as_a_biosorbent_for_Cu_II__ions_removal_from_the_aqueous_solutions_ L2 - https://linkinghub.elsevier.com/retrieve/pii/S0960-8524(07)00759-6 DB - PRIME DP - Unbound Medicine ER -