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Nickel-catalyzed beta-boration of alpha,beta-unsaturated esters and amides with bis(pinacolato)diboron.
Org Lett. 2007 Nov 22; 9(24):5031-3.OL

Abstract

A nickel catalyst system for beta-boration of alpha,beta-unsaturated esters and amides with bis(pinacolato)diboron has been developed. The catalyst system enables the boration of di-, tri-, and tetrasubstituted substrates in good yields.

Authors+Show Affiliations

Hirano K
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
Yorimitsu H
No affiliation info available
Oshima K
No affiliation info available

MeSH

AmidesBoron CompoundsBoronic AcidsButanonesCatalysisEstersMolecular StructureNickelOrganometallic CompoundsStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

17973483

Citation

Hirano, Koji, et al. "Nickel-catalyzed Beta-boration of Alpha,beta-unsaturated Esters and Amides With Bis(pinacolato)diboron." Organic Letters, vol. 9, no. 24, 2007, pp. 5031-3.
Hirano K, Yorimitsu H, Oshima K. Nickel-catalyzed beta-boration of alpha,beta-unsaturated esters and amides with bis(pinacolato)diboron. Org Lett. 2007;9(24):5031-3.
Hirano, K., Yorimitsu, H., & Oshima, K. (2007). Nickel-catalyzed beta-boration of alpha,beta-unsaturated esters and amides with bis(pinacolato)diboron. Organic Letters, 9(24), 5031-3.
Hirano K, Yorimitsu H, Oshima K. Nickel-catalyzed Beta-boration of Alpha,beta-unsaturated Esters and Amides With Bis(pinacolato)diboron. Org Lett. 2007 Nov 22;9(24):5031-3. PubMed PMID: 17973483.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Nickel-catalyzed beta-boration of alpha,beta-unsaturated esters and amides with bis(pinacolato)diboron. AU - Hirano,Koji, AU - Yorimitsu,Hideki, AU - Oshima,Koichiro, Y1 - 2007/11/01/ PY - 2007/11/2/pubmed PY - 2008/1/26/medline PY - 2007/11/2/entrez SP - 5031 EP - 3 JF - Organic letters JO - Org Lett VL - 9 IS - 24 N2 - A nickel catalyst system for beta-boration of alpha,beta-unsaturated esters and amides with bis(pinacolato)diboron has been developed. The catalyst system enables the boration of di-, tri-, and tetrasubstituted substrates in good yields. SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/17973483/Nickel_catalyzed_beta_boration_of_alphabeta_unsaturated_esters_and_amides_with_bis_pinacolato_diboron_ DB - PRIME DP - Unbound Medicine ER -