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Fast, efficient Ru(IV)-catalysed regioselective allylation of indoles using allyl alcohol (without additives) under mild conditions.
Chem Commun (Camb). 2007 Nov 28CC

Abstract

The new Ru(IV) salt, [Ru(eta(3)-C(3)H(5))(Cp*)(CH(3)CN)(2)](PF(6))(2), is an excellent catalyst for the regioselective allylation of a variety of indole compounds using allyl alcohol as substrate; there are no co-catalysts required in this chemistry and the yields and reaction conditions are very favorable.

Authors+Show Affiliations

Zaitsev AB
Laboratory of Inorganic Chemistry, ETHZ, Hönggerberg, CH-8093, Zürich, Switzerland.
Gruber S
No affiliation info available
Pregosin PS
No affiliation info available

MeSH

AlkylationCatalysisIndolesMolecular StructureOrganometallic CompoundsPropanolsRutheniumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

17989835

Citation

Zaitsev, Alexey B., et al. "Fast, Efficient Ru(IV)-catalysed Regioselective Allylation of Indoles Using Allyl Alcohol (without Additives) Under Mild Conditions." Chemical Communications (Cambridge, England), 2007, pp. 4692-3.
Zaitsev AB, Gruber S, Pregosin PS. Fast, efficient Ru(IV)-catalysed regioselective allylation of indoles using allyl alcohol (without additives) under mild conditions. Chem Commun (Camb). 2007.
Zaitsev, A. B., Gruber, S., & Pregosin, P. S. (2007). Fast, efficient Ru(IV)-catalysed regioselective allylation of indoles using allyl alcohol (without additives) under mild conditions. Chemical Communications (Cambridge, England), (44), 4692-3.
Zaitsev AB, Gruber S, Pregosin PS. Fast, Efficient Ru(IV)-catalysed Regioselective Allylation of Indoles Using Allyl Alcohol (without Additives) Under Mild Conditions. Chem Commun (Camb). 2007 Nov 28;(44)4692-3. PubMed PMID: 17989835.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Fast, efficient Ru(IV)-catalysed regioselective allylation of indoles using allyl alcohol (without additives) under mild conditions. AU - Zaitsev,Alexey B, AU - Gruber,Stefan, AU - Pregosin,Paul S, Y1 - 2007/10/15/ PY - 2007/11/9/pubmed PY - 2008/1/25/medline PY - 2007/11/9/entrez SP - 4692 EP - 3 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) IS - 44 N2 - The new Ru(IV) salt, [Ru(eta(3)-C(3)H(5))(Cp*)(CH(3)CN)(2)](PF(6))(2), is an excellent catalyst for the regioselective allylation of a variety of indole compounds using allyl alcohol as substrate; there are no co-catalysts required in this chemistry and the yields and reaction conditions are very favorable. SN - 1359-7345 UR - https://www.unboundmedicine.com/medline/citation/17989835/Fast_efficient_Ru_IV__catalysed_regioselective_allylation_of_indoles_using_allyl_alcohol__without_additives__under_mild_conditions_ DB - PRIME DP - Unbound Medicine ER -