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Highly enantioselective aza-Henry reaction of N-tosyl imines catalyzed by N,N'-dioxide-Cu(I) complexes.
J Org Chem. 2007 Dec 21; 72(26):10302-4.JO

Abstract

The N,N'-dioxide-Cu(I) complexes have been developed to catalyze the addition of nitromethane to N-tosyl aldimines. The aza-Henry reaction proceeds smoothly affording the corresponding nitro amines in good yields with high enantioselectivities. A catalytic cycle is proposed to explain the origin of reactivity.

Authors+Show Affiliations

Zhou H
Key Laboratory of Green Chemistry & Technology (Sichuan University), Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China.
Peng D
No affiliation info available
Qin B
No affiliation info available
Hou Z
No affiliation info available
Liu X
No affiliation info available
Feng X
No affiliation info available

MeSH

Aza CompoundsCatalysisCopperIminesMolecular StructureOrganometallic CompoundsStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

18044933

Citation

Zhou, Hui, et al. "Highly Enantioselective aza-Henry Reaction of N-tosyl Imines Catalyzed By N,N'-dioxide-Cu(I) Complexes." The Journal of Organic Chemistry, vol. 72, no. 26, 2007, pp. 10302-4.
Zhou H, Peng D, Qin B, et al. Highly enantioselective aza-Henry reaction of N-tosyl imines catalyzed by N,N'-dioxide-Cu(I) complexes. J Org Chem. 2007;72(26):10302-4.
Zhou, H., Peng, D., Qin, B., Hou, Z., Liu, X., & Feng, X. (2007). Highly enantioselective aza-Henry reaction of N-tosyl imines catalyzed by N,N'-dioxide-Cu(I) complexes. The Journal of Organic Chemistry, 72(26), 10302-4.
Zhou H, et al. Highly Enantioselective aza-Henry Reaction of N-tosyl Imines Catalyzed By N,N'-dioxide-Cu(I) Complexes. J Org Chem. 2007 Dec 21;72(26):10302-4. PubMed PMID: 18044933.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Highly enantioselective aza-Henry reaction of N-tosyl imines catalyzed by N,N'-dioxide-Cu(I) complexes. AU - Zhou,Hui, AU - Peng,Dan, AU - Qin,Bo, AU - Hou,Zongrui, AU - Liu,Xiaohua, AU - Feng,Xiaoming, Y1 - 2007/11/29/ PY - 2007/11/30/pubmed PY - 2008/3/26/medline PY - 2007/11/30/entrez SP - 10302 EP - 4 JF - The Journal of organic chemistry JO - J Org Chem VL - 72 IS - 26 N2 - The N,N'-dioxide-Cu(I) complexes have been developed to catalyze the addition of nitromethane to N-tosyl aldimines. The aza-Henry reaction proceeds smoothly affording the corresponding nitro amines in good yields with high enantioselectivities. A catalytic cycle is proposed to explain the origin of reactivity. SN - 0022-3263 UR - https://www.unboundmedicine.com/medline/citation/18044933/Highly_enantioselective_aza_Henry_reaction_of_N_tosyl_imines_catalyzed_by_NN'_dioxide_Cu_I__complexes_ DB - PRIME DP - Unbound Medicine ER -