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Palladium-catalyzed hydrophenylation of alkynes with sodium tetraphenylborate under mild conditions.
J Org Chem. 2008 Jan 18; 73(2):558-62.JO

Abstract

In an aqueous solution of acetic acid, PdCl2(PPh3)2 showed high catalytic activity for the hydrophenylation of both terminal and internal alkynes with sodium tetraphenylborate (NaBPh4) under mild conditions, affording phenyl alkenes in moderate to excellent yields.

Authors+Show Affiliations

Zeng H
Department of Chemistry, Tsinghua University, Innovative Catalysis Program, Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Beijing 100084, China.
Hua R
No affiliation info available

MeSH

AlkenesAlkynesCatalysisMolecular StructureOrganometallic CompoundsPalladiumStereoisomerismTetraphenylborate

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

18078346

Citation

Zeng, Hanxiang, and Ruimao Hua. "Palladium-catalyzed Hydrophenylation of Alkynes With Sodium Tetraphenylborate Under Mild Conditions." The Journal of Organic Chemistry, vol. 73, no. 2, 2008, pp. 558-62.
Zeng H, Hua R. Palladium-catalyzed hydrophenylation of alkynes with sodium tetraphenylborate under mild conditions. J Org Chem. 2008;73(2):558-62.
Zeng, H., & Hua, R. (2008). Palladium-catalyzed hydrophenylation of alkynes with sodium tetraphenylborate under mild conditions. The Journal of Organic Chemistry, 73(2), 558-62.
Zeng H, Hua R. Palladium-catalyzed Hydrophenylation of Alkynes With Sodium Tetraphenylborate Under Mild Conditions. J Org Chem. 2008 Jan 18;73(2):558-62. PubMed PMID: 18078346.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Palladium-catalyzed hydrophenylation of alkynes with sodium tetraphenylborate under mild conditions. AU - Zeng,Hanxiang, AU - Hua,Ruimao, Y1 - 2007/12/14/ PY - 2007/12/15/pubmed PY - 2008/3/25/medline PY - 2007/12/15/entrez SP - 558 EP - 62 JF - The Journal of organic chemistry JO - J Org Chem VL - 73 IS - 2 N2 - In an aqueous solution of acetic acid, PdCl2(PPh3)2 showed high catalytic activity for the hydrophenylation of both terminal and internal alkynes with sodium tetraphenylborate (NaBPh4) under mild conditions, affording phenyl alkenes in moderate to excellent yields. SN - 0022-3263 UR - https://www.unboundmedicine.com/medline/citation/18078346/Palladium_catalyzed_hydrophenylation_of_alkynes_with_sodium_tetraphenylborate_under_mild_conditions_ DB - PRIME DP - Unbound Medicine ER -