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Chiral N-heterocyclic carbene--Pd(0)-catalyzed asymmetric diamination of conjugated dienes and triene.
J Org Chem. 2008 Jan 18; 73(2):749-51.JO

Abstract

Studies show that a variety of conjugated dienes and triene can be enantioselectively diaminated using di-tert-butyldiaziridinone as nitrogen source and chiral N-heterocyclic carbene-Pd(0) complex as catalyst in good enantioselectivity (62-91% ee) with high regio- and diastereoselectivity.

Authors+Show Affiliations

Xu L
Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.
Shi Y
No affiliation info available

MeSH

AlkenesAminationAziridinesCatalysisHeterocyclic CompoundsHydrocarbonsKetonesMethaneMolecular StructurePalladiumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

18095707

Citation

Xu, Liang, and Yian Shi. "Chiral N-heterocyclic carbene--Pd(0)-catalyzed Asymmetric Diamination of Conjugated Dienes and Triene." The Journal of Organic Chemistry, vol. 73, no. 2, 2008, pp. 749-51.
Xu L, Shi Y. Chiral N-heterocyclic carbene--Pd(0)-catalyzed asymmetric diamination of conjugated dienes and triene. J Org Chem. 2008;73(2):749-51.
Xu, L., & Shi, Y. (2008). Chiral N-heterocyclic carbene--Pd(0)-catalyzed asymmetric diamination of conjugated dienes and triene. The Journal of Organic Chemistry, 73(2), 749-51.
Xu L, Shi Y. Chiral N-heterocyclic carbene--Pd(0)-catalyzed Asymmetric Diamination of Conjugated Dienes and Triene. J Org Chem. 2008 Jan 18;73(2):749-51. PubMed PMID: 18095707.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Chiral N-heterocyclic carbene--Pd(0)-catalyzed asymmetric diamination of conjugated dienes and triene. AU - Xu,Liang, AU - Shi,Yian, Y1 - 2007/12/21/ PY - 2007/12/22/pubmed PY - 2008/3/25/medline PY - 2007/12/22/entrez SP - 749 EP - 51 JF - The Journal of organic chemistry JO - J Org Chem VL - 73 IS - 2 N2 - Studies show that a variety of conjugated dienes and triene can be enantioselectively diaminated using di-tert-butyldiaziridinone as nitrogen source and chiral N-heterocyclic carbene-Pd(0) complex as catalyst in good enantioselectivity (62-91% ee) with high regio- and diastereoselectivity. SN - 0022-3263 UR - https://www.unboundmedicine.com/medline/citation/18095707/Chiral_N_heterocyclic_carbene__Pd_0__catalyzed_asymmetric_diamination_of_conjugated_dienes_and_triene_ DB - PRIME DP - Unbound Medicine ER -