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Studies on the capability and behavior of adsorption of thallium on nano-Al(2)O(3).
J Hazard Mater. 2008 Sep 15; 157(2-3):352-7.JH

Abstract

A novel sorbent, nano-Al(2)O(3) was employed for the removal of thallium from aqueous solution in batch equilibrium experiments, in order to investigate its adsorption properties. The removal percentage of thallium by the sorbent increased with increasing pH from 1 to 5. The adsorption capacities and removal percentage of Tl(III) onto nano-Al(2)O(3) were evaluated as a function of the solution concentration and temperature. Results have been analyzed by the Langmuir, Freundlich adsorption isotherms. Adsorption isothermal data could be well interpreted by the Langmuir model. The mean energy of adsorption 9.32 kJ mol(-1) was calculated from the Dubinin-Radushkevich (D-R) adsorption isotherm. The kinetic experimental data properly correlated with the second-order kinetic model. The thermodynamic parameters for the process of adsorption have been estimated. The DeltaH(0) and DeltaG(0) values of thallium(III) adsorption on nano-Al(2)O(3) showed endothermic adsorption.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Zhang L
College of Chemistry, Liaoning University, Shenyang, PR China. zhanglei63@126.com <zhanglei63@126.com>
Huang T
No affiliation info available
Zhang M
No affiliation info available
Guo X
No affiliation info available
Yuan Z
No affiliation info available

MeSH

AdsorptionAluminum OxideHydrogen-Ion ConcentrationKineticsNanoparticlesThalliumThermodynamicsWater Pollutants, Chemical

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

18280034

Citation

Zhang, Lei, et al. "Studies On the Capability and Behavior of Adsorption of Thallium On Nano-Al(2)O(3)." Journal of Hazardous Materials, vol. 157, no. 2-3, 2008, pp. 352-7.
Zhang L, Huang T, Zhang M, et al. Studies on the capability and behavior of adsorption of thallium on nano-Al(2)O(3). J Hazard Mater. 2008;157(2-3):352-7.
Zhang, L., Huang, T., Zhang, M., Guo, X., & Yuan, Z. (2008). Studies on the capability and behavior of adsorption of thallium on nano-Al(2)O(3). Journal of Hazardous Materials, 157(2-3), 352-7. https://doi.org/10.1016/j.jhazmat.2008.01.005
Zhang L, et al. Studies On the Capability and Behavior of Adsorption of Thallium On Nano-Al(2)O(3). J Hazard Mater. 2008 Sep 15;157(2-3):352-7. PubMed PMID: 18280034.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Studies on the capability and behavior of adsorption of thallium on nano-Al(2)O(3). AU - Zhang,Lei, AU - Huang,Ting, AU - Zhang,Min, AU - Guo,Xingjia, AU - Yuan,Zhu, Y1 - 2008/01/11/ PY - 2007/05/11/received PY - 2007/12/29/revised PY - 2008/01/03/accepted PY - 2008/2/19/pubmed PY - 2009/1/8/medline PY - 2008/2/19/entrez SP - 352 EP - 7 JF - Journal of hazardous materials JO - J Hazard Mater VL - 157 IS - 2-3 N2 - A novel sorbent, nano-Al(2)O(3) was employed for the removal of thallium from aqueous solution in batch equilibrium experiments, in order to investigate its adsorption properties. The removal percentage of thallium by the sorbent increased with increasing pH from 1 to 5. The adsorption capacities and removal percentage of Tl(III) onto nano-Al(2)O(3) were evaluated as a function of the solution concentration and temperature. Results have been analyzed by the Langmuir, Freundlich adsorption isotherms. Adsorption isothermal data could be well interpreted by the Langmuir model. The mean energy of adsorption 9.32 kJ mol(-1) was calculated from the Dubinin-Radushkevich (D-R) adsorption isotherm. The kinetic experimental data properly correlated with the second-order kinetic model. The thermodynamic parameters for the process of adsorption have been estimated. The DeltaH(0) and DeltaG(0) values of thallium(III) adsorption on nano-Al(2)O(3) showed endothermic adsorption. SN - 0304-3894 UR - https://www.unboundmedicine.com/medline/citation/18280034/Studies_on_the_capability_and_behavior_of_adsorption_of_thallium_on_nano_Al_2_O_3__ DB - PRIME DP - Unbound Medicine ER -