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Palladium-catalysed cis- and trans-silaboration of terminal alkynes: complementary access to stereo-defined trisubstituted alkenes.
Chem Commun (Camb). 2008 Mar 28CC

Abstract

Palladium-catalysed cis- and trans-silaboration of terminal alkynes has been developed via the addition of (chlorodimethylsilyl)pinacolborane, followed by a one-pot conversion of the chloro group on the silicon atom to an isopropoxy group.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Ohmura T
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
Oshima K
No affiliation info available
Suginome M
No affiliation info available

MeSH

AlkenesAlkynesBoranesCatalysisMolecular StructureOrganometallic CompoundsPalladiumSilanesStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

18338041

Citation

Ohmura, Toshimichi, et al. "Palladium-catalysed Cis- and Trans-silaboration of Terminal Alkynes: Complementary Access to Stereo-defined Trisubstituted Alkenes." Chemical Communications (Cambridge, England), 2008, pp. 1416-8.
Ohmura T, Oshima K, Suginome M. Palladium-catalysed cis- and trans-silaboration of terminal alkynes: complementary access to stereo-defined trisubstituted alkenes. Chem Commun (Camb). 2008.
Ohmura, T., Oshima, K., & Suginome, M. (2008). Palladium-catalysed cis- and trans-silaboration of terminal alkynes: complementary access to stereo-defined trisubstituted alkenes. Chemical Communications (Cambridge, England), (12), 1416-8. https://doi.org/10.1039/b800181b
Ohmura T, Oshima K, Suginome M. Palladium-catalysed Cis- and Trans-silaboration of Terminal Alkynes: Complementary Access to Stereo-defined Trisubstituted Alkenes. Chem Commun (Camb). 2008 Mar 28;(12)1416-8. PubMed PMID: 18338041.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Palladium-catalysed cis- and trans-silaboration of terminal alkynes: complementary access to stereo-defined trisubstituted alkenes. AU - Ohmura,Toshimichi, AU - Oshima,Kazuyuki, AU - Suginome,Michinori, Y1 - 2008/02/18/ PY - 2008/3/14/pubmed PY - 2008/5/31/medline PY - 2008/3/14/entrez SP - 1416 EP - 8 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) IS - 12 N2 - Palladium-catalysed cis- and trans-silaboration of terminal alkynes has been developed via the addition of (chlorodimethylsilyl)pinacolborane, followed by a one-pot conversion of the chloro group on the silicon atom to an isopropoxy group. SN - 1359-7345 UR - https://www.unboundmedicine.com/medline/citation/18338041/Palladium_catalysed_cis__and_trans_silaboration_of_terminal_alkynes:_complementary_access_to_stereo_defined_trisubstituted_alkenes_ DB - PRIME DP - Unbound Medicine ER -