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Ir-catalyzed regio- and enantioselective Friedel-Crafts-type allylic alkylation of indoles.
Org Lett. 2008 May 01; 10(9):1815-8.OL

Abstract

Highly regio- and enantioselective Ir-catalyzed Friedel-Crafts type allylic alkylation of indoles have been realized using [Ir(COD)Cl]2/phosphoramidite ligand 1a, affording the branched products with up to >97/3 branched-linear ratio and 92% ee.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Liu WB
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, China.
He H
No affiliation info available
Dai LX
No affiliation info available
You SL
No affiliation info available

MeSH

AlkylationCatalysisIndolesIridium

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

18386906

Citation

Liu, Wen-Bo, et al. "Ir-catalyzed Regio- and Enantioselective Friedel-Crafts-type Allylic Alkylation of Indoles." Organic Letters, vol. 10, no. 9, 2008, pp. 1815-8.
Liu WB, He H, Dai LX, et al. Ir-catalyzed regio- and enantioselective Friedel-Crafts-type allylic alkylation of indoles. Org Lett. 2008;10(9):1815-8.
Liu, W. B., He, H., Dai, L. X., & You, S. L. (2008). Ir-catalyzed regio- and enantioselective Friedel-Crafts-type allylic alkylation of indoles. Organic Letters, 10(9), 1815-8. https://doi.org/10.1021/ol800409d
Liu WB, et al. Ir-catalyzed Regio- and Enantioselective Friedel-Crafts-type Allylic Alkylation of Indoles. Org Lett. 2008 May 1;10(9):1815-8. PubMed PMID: 18386906.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Ir-catalyzed regio- and enantioselective Friedel-Crafts-type allylic alkylation of indoles. AU - Liu,Wen-Bo, AU - He,Hu, AU - Dai,Li-Xin, AU - You,Shu-Li, Y1 - 2008/04/03/ PY - 2008/4/5/pubmed PY - 2008/8/8/medline PY - 2008/4/5/entrez SP - 1815 EP - 8 JF - Organic letters JO - Org Lett VL - 10 IS - 9 N2 - Highly regio- and enantioselective Ir-catalyzed Friedel-Crafts type allylic alkylation of indoles have been realized using [Ir(COD)Cl]2/phosphoramidite ligand 1a, affording the branched products with up to >97/3 branched-linear ratio and 92% ee. SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/18386906/Ir_catalyzed_regio__and_enantioselective_Friedel_Crafts_type_allylic_alkylation_of_indoles_ DB - PRIME DP - Unbound Medicine ER -
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