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Palladium-catalyzed three-component coupling of arynes with allylic acetates or halides and terminal alkynes promoted by cuprous iodide.
Chem Commun (Camb). 2008 May 14CC

Abstract

Benzynes react with allylic acetates or halides and terminal alkynes in the presence of Pd(PPh3)4, CuI and CsF in CH3CN at 50 degrees C for 5 h to give 1-allyl-2-alkynylbenzene derivatives in good to excellent yields.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Bhuvaneswari S
Department of Chemistry, National Tsing Hua University, Hsinchu, 30013, Taiwan.
Jeganmohan M
No affiliation info available
Yang MC
No affiliation info available
Cheng CH
No affiliation info available

MeSH

AcetatesAlkynesAllyl CompoundsBenzene DerivativesCatalysisCopperHydrocarbons, HalogenatedIodidesMolecular StructureOrganometallic CompoundsPalladiumStereoisomerism

Pub Type(s)

Journal Article

Language

eng

PubMed ID

18438501

Citation

Bhuvaneswari, Sivakolundu, et al. "Palladium-catalyzed Three-component Coupling of Arynes With Allylic Acetates or Halides and Terminal Alkynes Promoted By Cuprous Iodide." Chemical Communications (Cambridge, England), 2008, pp. 2158-60.
Bhuvaneswari S, Jeganmohan M, Yang MC, et al. Palladium-catalyzed three-component coupling of arynes with allylic acetates or halides and terminal alkynes promoted by cuprous iodide. Chem Commun (Camb). 2008.
Bhuvaneswari, S., Jeganmohan, M., Yang, M. C., & Cheng, C. H. (2008). Palladium-catalyzed three-component coupling of arynes with allylic acetates or halides and terminal alkynes promoted by cuprous iodide. Chemical Communications (Cambridge, England), (18), 2158-60. https://doi.org/10.1039/b800118a
Bhuvaneswari S, et al. Palladium-catalyzed Three-component Coupling of Arynes With Allylic Acetates or Halides and Terminal Alkynes Promoted By Cuprous Iodide. Chem Commun (Camb). 2008 May 14;(18)2158-60. PubMed PMID: 18438501.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Palladium-catalyzed three-component coupling of arynes with allylic acetates or halides and terminal alkynes promoted by cuprous iodide. AU - Bhuvaneswari,Sivakolundu, AU - Jeganmohan,Masilamani, AU - Yang,Ming-Che, AU - Cheng,Chien-Hong, Y1 - 2008/03/03/ PY - 2008/4/29/pubmed PY - 2008/7/17/medline PY - 2008/4/29/entrez SP - 2158 EP - 60 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) IS - 18 N2 - Benzynes react with allylic acetates or halides and terminal alkynes in the presence of Pd(PPh3)4, CuI and CsF in CH3CN at 50 degrees C for 5 h to give 1-allyl-2-alkynylbenzene derivatives in good to excellent yields. SN - 1359-7345 UR - https://www.unboundmedicine.com/medline/citation/18438501/Palladium_catalyzed_three_component_coupling_of_arynes_with_allylic_acetates_or_halides_and_terminal_alkynes_promoted_by_cuprous_iodide_ DB - PRIME DP - Unbound Medicine ER -