Tags

Type your tag names separated by a space and hit enter

Olefin metathesis catalyst: stabilization effect of backbone substitutions of N-heterocyclic carbene.
Org Lett. 2008 Jul 03; 10(13):2693-6.OL

Abstract

Ruthenium olefin metathesis catalysts bearing an N-phenyl-substituted N-heterocyclic carbene (NHC) ligand that are resistant to decomposition through C-H activation have been prepared and tested in ring closing metathesis (RCM), cross metathesis (CM), and ROMP reactions. The N, N'-diphenyl-substituted NHC complex proved to be one of the most efficient catalysts in RCM to form tetrasubstituted olefins.

Links

Publisher Full Text (DOI)

Authors+Show Affiliations

Chung CK
The Arnold and Mabel Beckman Laboratories for Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA.
Grubbs RH
No affiliation info available

MeSH

AlkenesCatalysisCrystallography, X-RayHeterocyclic CompoundsMethaneModels, MolecularMolecular StructureRuthenium

Pub Type(s)

Journal Article
Research Support, N.I.H., Extramural

Language

eng

PubMed ID

18510331

Citation

Chung, Cheol K., and Robert H. Grubbs. "Olefin Metathesis Catalyst: Stabilization Effect of Backbone Substitutions of N-heterocyclic Carbene." Organic Letters, vol. 10, no. 13, 2008, pp. 2693-6.
Chung CK, Grubbs RH. Olefin metathesis catalyst: stabilization effect of backbone substitutions of N-heterocyclic carbene. Org Lett. 2008;10(13):2693-6.
Chung, C. K., & Grubbs, R. H. (2008). Olefin metathesis catalyst: stabilization effect of backbone substitutions of N-heterocyclic carbene. Organic Letters, 10(13), 2693-6. https://doi.org/10.1021/ol800824h
Chung CK, Grubbs RH. Olefin Metathesis Catalyst: Stabilization Effect of Backbone Substitutions of N-heterocyclic Carbene. Org Lett. 2008 Jul 3;10(13):2693-6. PubMed PMID: 18510331.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Olefin metathesis catalyst: stabilization effect of backbone substitutions of N-heterocyclic carbene. AU - Chung,Cheol K, AU - Grubbs,Robert H, Y1 - 2008/05/30/ PY - 2008/5/31/pubmed PY - 2008/9/17/medline PY - 2008/5/31/entrez SP - 2693 EP - 6 JF - Organic letters JO - Org Lett VL - 10 IS - 13 N2 - Ruthenium olefin metathesis catalysts bearing an N-phenyl-substituted N-heterocyclic carbene (NHC) ligand that are resistant to decomposition through C-H activation have been prepared and tested in ring closing metathesis (RCM), cross metathesis (CM), and ROMP reactions. The N, N'-diphenyl-substituted NHC complex proved to be one of the most efficient catalysts in RCM to form tetrasubstituted olefins. SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/18510331/Olefin_metathesis_catalyst:_stabilization_effect_of_backbone_substitutions_of_N_heterocyclic_carbene_ L2 - https://doi.org/10.1021/ol800824h DB - PRIME DP - Unbound Medicine ER -