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Highly regioselective isomerization-hydroformylation of internal olefins to linear aldehyde using rh complexes with tetraphosphorus ligands.
Org Lett. 2008 Aug 21; 10(16):3469-72.OL

Abstract

A series of new pyrrole-based tetraphosphorus ligands were synthesized and used for Rh-catalyzed isomerization-hydroformylation of internal olefins. It was found that the substituents at the 3,3',5,5'-positions of the biphenyl greatly effected the linear selectivity, and the alkyl-substituted tetraphosphorus ligands gave the best results (for 2-octene, n: i up to 207, for 2-hexene, n: i up to 362).

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Publisher Full Text (DOI)

Authors+Show Affiliations

Yu S
Department of Chemistry and Chemical Biology and Department of Pharmaceutical Chemistry, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854-8020, USA.
Chie YM
No affiliation info available
Guan ZH
No affiliation info available
Zhang X
No affiliation info available

MeSH

AldehydesAlkenesLigandsMolecular StructureOrganometallic CompoundsOrganophosphorus CompoundsPyrrolesRhodiumStereoisomerism

Pub Type(s)

Journal Article
Research Support, N.I.H., Extramural
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

18616258

Citation

Yu, Shichao, et al. "Highly Regioselective Isomerization-hydroformylation of Internal Olefins to Linear Aldehyde Using Rh Complexes With Tetraphosphorus Ligands." Organic Letters, vol. 10, no. 16, 2008, pp. 3469-72.
Yu S, Chie YM, Guan ZH, et al. Highly regioselective isomerization-hydroformylation of internal olefins to linear aldehyde using rh complexes with tetraphosphorus ligands. Org Lett. 2008;10(16):3469-72.
Yu, S., Chie, Y. M., Guan, Z. H., & Zhang, X. (2008). Highly regioselective isomerization-hydroformylation of internal olefins to linear aldehyde using rh complexes with tetraphosphorus ligands. Organic Letters, 10(16), 3469-72. https://doi.org/10.1021/ol801247v
Yu S, et al. Highly Regioselective Isomerization-hydroformylation of Internal Olefins to Linear Aldehyde Using Rh Complexes With Tetraphosphorus Ligands. Org Lett. 2008 Aug 21;10(16):3469-72. PubMed PMID: 18616258.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Highly regioselective isomerization-hydroformylation of internal olefins to linear aldehyde using rh complexes with tetraphosphorus ligands. AU - Yu,Shichao, AU - Chie,Yu-Ming, AU - Guan,Zheng-Hui, AU - Zhang,Xumu, Y1 - 2008/07/11/ PY - 2008/7/12/pubmed PY - 2008/10/22/medline PY - 2008/7/12/entrez SP - 3469 EP - 72 JF - Organic letters JO - Org Lett VL - 10 IS - 16 N2 - A series of new pyrrole-based tetraphosphorus ligands were synthesized and used for Rh-catalyzed isomerization-hydroformylation of internal olefins. It was found that the substituents at the 3,3',5,5'-positions of the biphenyl greatly effected the linear selectivity, and the alkyl-substituted tetraphosphorus ligands gave the best results (for 2-octene, n: i up to 207, for 2-hexene, n: i up to 362). SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/18616258/Highly_regioselective_isomerization_hydroformylation_of_internal_olefins_to_linear_aldehyde_using_rh_complexes_with_tetraphosphorus_ligands_ L2 - https://doi.org/10.1021/ol801247v DB - PRIME DP - Unbound Medicine ER -