Phosphinite- and phosphite-based Type I palladacycles as highly active catalysts for addition reactions of arylboronic acids with aldehydes, α,β-unsaturated ketones, α-ketoesters, and aldimines.
Tetrahedron Lett. 2007 Jul 23; 48(30):5283-5288.TL

Abstract

Phosphinite- and phosphite-based Type I palladacycle-catalyzed additions of arylboronic acids with aldehydes, α,β-unsaturated ketones, α-ketoesters and aldimines are described. Our study showed that readily available phosphinite- and phosphite-based Type I palladacycles could possess higher catalytic activity than phosphine-based palladacycles and were highly active, practical catalysts. Our study may pave the road for development of optically active phosphinite- and phosphite-based palladacycles for asymmetric catalysis.

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Authors+Show Affiliations

He P

Department of Chemistry, College of Staten Island and the Graduate Center of the City University of New York, Staten Island, New York 10314.

Lu Y

No affiliation info available

Hu QS

No affiliation info available

Pub Type(s)

Journal Article

Language

eng

PubMed ID

18648490

Citation

He, Ping, et al. "Phosphinite- and Phosphite-based Type I Palladacycles as Highly Active Catalysts for Addition Reactions of Arylboronic Acids With Aldehydes, Α,β-unsaturated Ketones, Α-ketoesters, and Aldimines." Tetrahedron Letters, vol. 48, no. 30, 2007, pp. 5283-5288.

He P, Lu Y, Hu QS. Phosphinite- and phosphite-based Type I palladacycles as highly active catalysts for addition reactions of arylboronic acids with aldehydes, α,β-unsaturated ketones, α-ketoesters, and aldimines. Tetrahedron Lett. 2007;48(30):5283-5288.

He, P., Lu, Y., & Hu, Q. S. (2007). Phosphinite- and phosphite-based Type I palladacycles as highly active catalysts for addition reactions of arylboronic acids with aldehydes, α,β-unsaturated ketones, α-ketoesters, and aldimines. Tetrahedron Letters, 48(30), 5283-5288.

He P, Lu Y, Hu QS. Phosphinite- and Phosphite-based Type I Palladacycles as Highly Active Catalysts for Addition Reactions of Arylboronic Acids With Aldehydes, Α,β-unsaturated Ketones, Α-ketoesters, and Aldimines. Tetrahedron Lett. 2007 Jul 23;48(30):5283-5288. PubMed PMID: 18648490.

* Article titles in AMA citation format should be in sentence-case

TY - JOUR T1 - Phosphinite- and phosphite-based Type I palladacycles as highly active catalysts for addition reactions of arylboronic acids with aldehydes, α,β-unsaturated ketones, α-ketoesters, and aldimines. AU - He,Ping, AU - Lu,Yong, AU - Hu,Qiao-Sheng, PY - 2008/7/24/pubmed PY - 2008/7/24/medline PY - 2008/7/24/entrez SP - 5283 EP - 5288 JF - Tetrahedron letters JO - Tetrahedron Lett VL - 48 IS - 30 N2 - Phosphinite- and phosphite-based Type I palladacycle-catalyzed additions of arylboronic acids with aldehydes, α,β-unsaturated ketones, α-ketoesters and aldimines are described. Our study showed that readily available phosphinite- and phosphite-based Type I palladacycles could possess higher catalytic activity than phosphine-based palladacycles and were highly active, practical catalysts. Our study may pave the road for development of optically active phosphinite- and phosphite-based palladacycles for asymmetric catalysis. SN - 0040-4039 UR - https://www.unboundmedicine.com/medline/citation/18648490/Phosphinite__and_phosphite_based_Type_I_palladacycles_as_highly_active_catalysts_for_addition_reactions_of_arylboronic_acids_with_aldehydes_αβ_unsaturated_ketones_α_ketoesters_and_aldimines_ L2 - https://www.ncbi.nlm.nih.gov/pmc/articles/pmid/18648490/ DB - PRIME DP - Unbound Medicine ER -

Tags

Phosphinite- and phosphite-based Type I palladacycles as highly active catalysts for addition reactions of arylboronic acids with aldehydes, α,β-unsaturated ketones, α-ketoesters, and aldimines.Tetrahedron Lett. 2007 Jul 23; 48(30):5283-5288.TL