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Asymmetric Michael addition of trisubstituted carbanion to nitroalkenes catalyzed by sodium demethylquinine salt in water.
Chirality. 2009 Jun; 21(6):600-3.C

Abstract

A mild method for the asymmetric synthesis of quaternary and tertiary carbon centers has been developed through Michael addition of trisubstituted carbon nucleophile to nitroalkenes catalyzed by low loading sodium demethylquinine salt in water.

Links

Publisher Full Text (DOI)

Authors+Show Affiliations

Chen FX
State Key Laboratory of Applied Organic Chemistry, Institute of Biochemistry and Molecular Biology, Lanzhou University, Lanzhou, Gansu 730000, China.
Shao C
No affiliation info available
Liu Q
No affiliation info available
Gong P
No affiliation info available
Liu CL
No affiliation info available
Wang R
No affiliation info available

MeSH

AlkenesCarbonCatalysisCrystallography, X-RayQuinineSaltsStereoisomerismSubstrate SpecificityWater

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

18752286

Citation

Chen, Fu-Xin, et al. "Asymmetric Michael Addition of Trisubstituted Carbanion to Nitroalkenes Catalyzed By Sodium Demethylquinine Salt in Water." Chirality, vol. 21, no. 6, 2009, pp. 600-3.
Chen FX, Shao C, Liu Q, et al. Asymmetric Michael addition of trisubstituted carbanion to nitroalkenes catalyzed by sodium demethylquinine salt in water. Chirality. 2009;21(6):600-3.
Chen, F. X., Shao, C., Liu, Q., Gong, P., Liu, C. L., & Wang, R. (2009). Asymmetric Michael addition of trisubstituted carbanion to nitroalkenes catalyzed by sodium demethylquinine salt in water. Chirality, 21(6), 600-3. https://doi.org/10.1002/chir.20651
Chen FX, et al. Asymmetric Michael Addition of Trisubstituted Carbanion to Nitroalkenes Catalyzed By Sodium Demethylquinine Salt in Water. Chirality. 2009;21(6):600-3. PubMed PMID: 18752286.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Asymmetric Michael addition of trisubstituted carbanion to nitroalkenes catalyzed by sodium demethylquinine salt in water. AU - Chen,Fu-Xin, AU - Shao,Cheng, AU - Liu,Qian, AU - Gong,Pin, AU - Liu,Chun-Liang, AU - Wang,Rui, PY - 2008/8/30/pubmed PY - 2009/7/1/medline PY - 2008/8/30/entrez SP - 600 EP - 3 JF - Chirality JO - Chirality VL - 21 IS - 6 N2 - A mild method for the asymmetric synthesis of quaternary and tertiary carbon centers has been developed through Michael addition of trisubstituted carbon nucleophile to nitroalkenes catalyzed by low loading sodium demethylquinine salt in water. SN - 1520-636X UR - https://www.unboundmedicine.com/medline/citation/18752286/Asymmetric_Michael_addition_of_trisubstituted_carbanion_to_nitroalkenes_catalyzed_by_sodium_demethylquinine_salt_in_water_ L2 - https://doi.org/10.1002/chir.20651 DB - PRIME DP - Unbound Medicine ER -