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Regiocontrolled addition of arylboronic acids to allenes using palladium and platinum catalysts.
Org Lett. 2008 Nov 20; 10(22):5183-6.OL

Abstract

Studies about the regiocontrolled addition of arylboronic acids to allenes using a palladium or a platinum catalyst have been described. The selectivity of the reaction can be altered by the choice of the metal reagent and base. Contrary to the formation of endo-olefinic products in the reactions using hydroxopalladium complex, predominant production of exo-olefinic products was observed by the reaction with hydroxoplatinum complex.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Yoshida M
Graduate School of Pharmaceutical Sciences, The University of Tokushima, Tokushima, Japan. yoshida@ph.tokushima-u.ac.jp
Matsuda K
No affiliation info available
Shoji Y
No affiliation info available
Gotou T
No affiliation info available
Ihara M
No affiliation info available
Shishido K
No affiliation info available

MeSH

AlkadienesBoronic AcidsCatalysisPalladiumPlatinumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

18939800

Citation

Yoshida, Masahiro, et al. "Regiocontrolled Addition of Arylboronic Acids to Allenes Using Palladium and Platinum Catalysts." Organic Letters, vol. 10, no. 22, 2008, pp. 5183-6.
Yoshida M, Matsuda K, Shoji Y, et al. Regiocontrolled addition of arylboronic acids to allenes using palladium and platinum catalysts. Org Lett. 2008;10(22):5183-6.
Yoshida, M., Matsuda, K., Shoji, Y., Gotou, T., Ihara, M., & Shishido, K. (2008). Regiocontrolled addition of arylboronic acids to allenes using palladium and platinum catalysts. Organic Letters, 10(22), 5183-6. https://doi.org/10.1021/ol8021484
Yoshida M, et al. Regiocontrolled Addition of Arylboronic Acids to Allenes Using Palladium and Platinum Catalysts. Org Lett. 2008 Nov 20;10(22):5183-6. PubMed PMID: 18939800.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Regiocontrolled addition of arylboronic acids to allenes using palladium and platinum catalysts. AU - Yoshida,Masahiro, AU - Matsuda,Kennosuke, AU - Shoji,Yasunobu, AU - Gotou,Takahiro, AU - Ihara,Masataka, AU - Shishido,Kozo, Y1 - 2008/10/22/ PY - 2008/10/23/pubmed PY - 2008/12/17/medline PY - 2008/10/23/entrez SP - 5183 EP - 6 JF - Organic letters JO - Org Lett VL - 10 IS - 22 N2 - Studies about the regiocontrolled addition of arylboronic acids to allenes using a palladium or a platinum catalyst have been described. The selectivity of the reaction can be altered by the choice of the metal reagent and base. Contrary to the formation of endo-olefinic products in the reactions using hydroxopalladium complex, predominant production of exo-olefinic products was observed by the reaction with hydroxoplatinum complex. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/18939800/Regiocontrolled_addition_of_arylboronic_acids_to_allenes_using_palladium_and_platinum_catalysts_ L2 - https://doi.org/10.1021/ol8021484 DB - PRIME DP - Unbound Medicine ER -