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Axial chirality control of tropos BIPHEP-Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation.
Chem Commun (Camb). 2008 Nov 07CC

Abstract

Diastereopure tropos Rh complexes bearing not only BIPHEP but also chiral dienes can be employed as highly enantioselective hydrogenation catalysts for an olefinic substrate.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Aikawa K
Department of Applied Chemistry, Tokyo Institute of Technology, Tokyo, 152-8552, Japan.
Takabayashi Y
No affiliation info available
Kawauchi S
No affiliation info available
Mikami K
No affiliation info available

Pub Type(s)

Journal Article

Language

eng

PubMed ID

18956033

Citation

Aikawa, Kohsuke, et al. "Axial Chirality Control of Tropos BIPHEP-Rh Complexes By Chiral Dienes: Synergy Effect in Catalytic Asymmetric Hydrogenation." Chemical Communications (Cambridge, England), 2008, pp. 5095-7.
Aikawa K, Takabayashi Y, Kawauchi S, et al. Axial chirality control of tropos BIPHEP-Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation. Chem Commun (Camb). 2008.
Aikawa, K., Takabayashi, Y., Kawauchi, S., & Mikami, K. (2008). Axial chirality control of tropos BIPHEP-Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation. Chemical Communications (Cambridge, England), (41), 5095-7. https://doi.org/10.1039/b809683j
Aikawa K, et al. Axial Chirality Control of Tropos BIPHEP-Rh Complexes By Chiral Dienes: Synergy Effect in Catalytic Asymmetric Hydrogenation. Chem Commun (Camb). 2008 Nov 7;(41)5095-7. PubMed PMID: 18956033.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Axial chirality control of tropos BIPHEP-Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation. AU - Aikawa,Kohsuke, AU - Takabayashi,Yūki, AU - Kawauchi,Susumu, AU - Mikami,Koichi, Y1 - 2008/09/30/ PY - 2008/10/29/pubmed PY - 2008/10/29/medline PY - 2008/10/29/entrez SP - 5095 EP - 7 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) IS - 41 N2 - Diastereopure tropos Rh complexes bearing not only BIPHEP but also chiral dienes can be employed as highly enantioselective hydrogenation catalysts for an olefinic substrate. SN - 1359-7345 UR - https://www.unboundmedicine.com/medline/citation/18956033/Axial_chirality_control_of_tropos_BIPHEP_Rh_complexes_by_chiral_dienes:_synergy_effect_in_catalytic_asymmetric_hydrogenation_ L2 - https://doi.org/10.1039/b809683j DB - PRIME DP - Unbound Medicine ER -