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Catalytic synthesis of oligoene and enyne derivatives through carbometalation of internal alkynes.
Chem Rec. 2008; 8(5):326-36.CR

Abstract

A number of new synthetic methods for pi-conjugated oligoene and enyne compounds are described. Thus, diene and higher oligoene derivatives are selectively constructed by palladium-catalyzed arylation reactions of internal alkynes in the presence of arylboronic acids or alkenes as terminators. In contrast, the synthesis of various enyne derivatives is achieved effectively by homo- or cross dimerization of alkynes under rhodium catalysis.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Satoh T
Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan. satoh@chem.eng.osaka-u.ac.jp
Tsurugi H
No affiliation info available
Miura M
No affiliation info available

MeSH

AlkenesAlkynesBoronic AcidsCatalysisMolecular StructureOrganometallic CompoundsPalladiumPolyenesRhodiumStereoisomerism

Pub Type(s)

Journal Article
Review

Language

eng

PubMed ID

18958852

Citation

Satoh, Tetsuya, et al. "Catalytic Synthesis of Oligoene and Enyne Derivatives Through Carbometalation of Internal Alkynes." Chemical Record (New York, N.Y.), vol. 8, no. 5, 2008, pp. 326-36.
Satoh T, Tsurugi H, Miura M. Catalytic synthesis of oligoene and enyne derivatives through carbometalation of internal alkynes. Chem Rec. 2008;8(5):326-36.
Satoh, T., Tsurugi, H., & Miura, M. (2008). Catalytic synthesis of oligoene and enyne derivatives through carbometalation of internal alkynes. Chemical Record (New York, N.Y.), 8(5), 326-36. https://doi.org/10.1002/tcr.20158
Satoh T, Tsurugi H, Miura M. Catalytic Synthesis of Oligoene and Enyne Derivatives Through Carbometalation of Internal Alkynes. Chem Rec. 2008;8(5):326-36. PubMed PMID: 18958852.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Catalytic synthesis of oligoene and enyne derivatives through carbometalation of internal alkynes. AU - Satoh,Tetsuya, AU - Tsurugi,Hayato, AU - Miura,Masahiro, PY - 2008/10/30/pubmed PY - 2008/12/17/medline PY - 2008/10/30/entrez SP - 326 EP - 36 JF - Chemical record (New York, N.Y.) JO - Chem Rec VL - 8 IS - 5 N2 - A number of new synthetic methods for pi-conjugated oligoene and enyne compounds are described. Thus, diene and higher oligoene derivatives are selectively constructed by palladium-catalyzed arylation reactions of internal alkynes in the presence of arylboronic acids or alkenes as terminators. In contrast, the synthesis of various enyne derivatives is achieved effectively by homo- or cross dimerization of alkynes under rhodium catalysis. SN - 1528-0691 UR - https://www.unboundmedicine.com/medline/citation/18958852/Catalytic_synthesis_of_oligoene_and_enyne_derivatives_through_carbometalation_of_internal_alkynes_ L2 - https://doi.org/10.1002/tcr.20158 DB - PRIME DP - Unbound Medicine ER -