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A modular approach to catalyst hydrophobicity for an asymmetric aldol reaction in a biphasic aqueous environment.
Org Biomol Chem. 2008 Nov 21; 6(22):4224-9.OB

Abstract

Catalyst 5, an ion pair consisting of a hydrophilic cation and a lipophilic anion, fulfils the solubility requirements needed to couple efficiency (enantioselectivities and anti-diastereoselectivities up to > or = 99%) and catalyst recyclability in asymmetric aldol reactions under aqueous biphasic conditions.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Lombardo M
Dipartimento di Chimica G. Ciamician, Università di Bologna, via Selmi 2, Bologna, Italy. marco.lombardo@unibo.it
Easwar S
No affiliation info available
De Marco A
No affiliation info available
Pasi F
No affiliation info available
Trombini C
No affiliation info available

MeSH

AcetatesAldehydesCatalysisHydrophobic and Hydrophilic InteractionsImidazolesProlineWater

Pub Type(s)

Journal Article

Language

eng

PubMed ID

18972054

Citation

Lombardo, Marco, et al. "A Modular Approach to Catalyst Hydrophobicity for an Asymmetric Aldol Reaction in a Biphasic Aqueous Environment." Organic & Biomolecular Chemistry, vol. 6, no. 22, 2008, pp. 4224-9.
Lombardo M, Easwar S, De Marco A, et al. A modular approach to catalyst hydrophobicity for an asymmetric aldol reaction in a biphasic aqueous environment. Org Biomol Chem. 2008;6(22):4224-9.
Lombardo, M., Easwar, S., De Marco, A., Pasi, F., & Trombini, C. (2008). A modular approach to catalyst hydrophobicity for an asymmetric aldol reaction in a biphasic aqueous environment. Organic & Biomolecular Chemistry, 6(22), 4224-9. https://doi.org/10.1039/b812607k
Lombardo M, et al. A Modular Approach to Catalyst Hydrophobicity for an Asymmetric Aldol Reaction in a Biphasic Aqueous Environment. Org Biomol Chem. 2008 Nov 21;6(22):4224-9. PubMed PMID: 18972054.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - A modular approach to catalyst hydrophobicity for an asymmetric aldol reaction in a biphasic aqueous environment. AU - Lombardo,Marco, AU - Easwar,Srinivasan, AU - De Marco,Alessandro, AU - Pasi,Filippo, AU - Trombini,Claudio, Y1 - 2008/09/29/ PY - 2008/10/31/pubmed PY - 2008/12/17/medline PY - 2008/10/31/entrez SP - 4224 EP - 9 JF - Organic & biomolecular chemistry JO - Org Biomol Chem VL - 6 IS - 22 N2 - Catalyst 5, an ion pair consisting of a hydrophilic cation and a lipophilic anion, fulfils the solubility requirements needed to couple efficiency (enantioselectivities and anti-diastereoselectivities up to > or = 99%) and catalyst recyclability in asymmetric aldol reactions under aqueous biphasic conditions. SN - 1477-0539 UR - https://www.unboundmedicine.com/medline/citation/18972054/A_modular_approach_to_catalyst_hydrophobicity_for_an_asymmetric_aldol_reaction_in_a_biphasic_aqueous_environment_ L2 - https://doi.org/10.1039/b812607k DB - PRIME DP - Unbound Medicine ER -