Highly diastereo- and enantioselective construction of both central and axial chiralities by Rh-catalyzed [2 + 2 + 2] cycloaddition.Org Biomol Chem. 2008 Dec 07; 6(23):4296-8.OB
Abstract
The cationic Rh-SEGPHOS complex catalyzed an intermolecular [2 + 2 + 2] cycloaddition of enynes, possessing an ortho-substituted aryl group on their alkyne terminus, with acetylenedicarboxylates. Bicyclic cyclohexa-1,3-dienes with both central and axial chiralities were obtained in extremely highly diastereo- and enantioselective manner.
Links
Pub Type(s)
Journal Article
Language
eng
PubMed ID
19005587
Citation
Shibata, Takanori, et al. "Highly Diastereo- and Enantioselective Construction of Both Central and Axial Chiralities By Rh-catalyzed [2 + 2 + 2] Cycloaddition." Organic & Biomolecular Chemistry, vol. 6, no. 23, 2008, pp. 4296-8.
Shibata T, Otomo M, Tahara YK, et al. Highly diastereo- and enantioselective construction of both central and axial chiralities by Rh-catalyzed [2 + 2 + 2] cycloaddition. Org Biomol Chem. 2008;6(23):4296-8.
Shibata, T., Otomo, M., Tahara, Y. K., & Endo, K. (2008). Highly diastereo- and enantioselective construction of both central and axial chiralities by Rh-catalyzed [2 + 2 + 2] cycloaddition. Organic & Biomolecular Chemistry, 6(23), 4296-8. https://doi.org/10.1039/b814014f
Shibata T, et al. Highly Diastereo- and Enantioselective Construction of Both Central and Axial Chiralities By Rh-catalyzed [2 + 2 + 2] Cycloaddition. Org Biomol Chem. 2008 Dec 7;6(23):4296-8. PubMed PMID: 19005587.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR
T1 - Highly diastereo- and enantioselective construction of both central and axial chiralities by Rh-catalyzed [2 + 2 + 2] cycloaddition.
AU - Shibata,Takanori,
AU - Otomo,Mayumi,
AU - Tahara,Yu-ki,
AU - Endo,Kohei,
Y1 - 2008/10/15/
PY - 2008/11/14/pubmed
PY - 2008/11/14/medline
PY - 2008/11/14/entrez
SP - 4296
EP - 8
JF - Organic & biomolecular chemistry
JO - Org Biomol Chem
VL - 6
IS - 23
N2 - The cationic Rh-SEGPHOS complex catalyzed an intermolecular [2 + 2 + 2] cycloaddition of enynes, possessing an ortho-substituted aryl group on their alkyne terminus, with acetylenedicarboxylates. Bicyclic cyclohexa-1,3-dienes with both central and axial chiralities were obtained in extremely highly diastereo- and enantioselective manner.
SN - 1477-0539
UR - https://www.unboundmedicine.com/medline/citation/19005587/Highly_diastereo__and_enantioselective_construction_of_both_central_and_axial_chiralities_by_Rh_catalyzed_[2_+_2_+_2]_cycloaddition_
L2 - https://doi.org/10.1039/b814014f
DB - PRIME
DP - Unbound Medicine
ER -
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