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Risk assessment of representative and priority pesticides, in surface water of the Alqueva reservoir (South of Portugal) using on-line solid phase extraction-liquid chromatography-tandem mass spectrometry.
Environ Int. 2009 Apr; 35(3):545-51.EI

Abstract

Surface waters located in intensive agricultural areas are more vulnerable to the pesticides contamination, which is a major concern if the water is intended to be used for human consumption. The aim of this study was to evaluate the presence and the distribution of pesticides in the Alqueva reservoir, an important source of water supply (South of Portugal), considering their representativeness in the agricultural practice of the area. For the analysis of pesticides risk impact we used the environmental quality standards in the field of water policy proposed recently by the European Commission. The pesticides belonging to the classes of phenylureas, triazines, chloroacetanilides, organophosphorous and thiocarbamates were analysed by on-line solid phase extraction-liquid chromatography-tandem mass spectrometry. The pesticides more frequently detected were atrazine, simazine, diuron and terbuthylazine. The highest levels of these pesticides were registered in spring, after pesticides treatment, namely in olive-tree and vine crops. The priority pesticides atrazine and diuron reached values above the annual average proposed in the European Union Legislation. The herbicide atrazine reached values that surpassed the proposed maximum allowable concentration (2,000 ng L(-1)). The sampling stations most affected by these pesticides were Sra. Ajuda, Lucefecit and Alcarrache, located in the northern part of the reservoir, closer to Spain where the agricultural activity is more intensive.

Authors+Show Affiliations

Departamento de Ciências do Ambiente, Escola Superior Agrária de Beja, Apartado 6158, 7801-908 Beja, Portugal. ppalma@esab.ipbeja.ptNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

19010545

Citation

Palma, P, et al. "Risk Assessment of Representative and Priority Pesticides, in Surface Water of the Alqueva Reservoir (South of Portugal) Using On-line Solid Phase Extraction-liquid Chromatography-tandem Mass Spectrometry." Environment International, vol. 35, no. 3, 2009, pp. 545-51.
Palma P, Kuster M, Alvarenga P, et al. Risk assessment of representative and priority pesticides, in surface water of the Alqueva reservoir (South of Portugal) using on-line solid phase extraction-liquid chromatography-tandem mass spectrometry. Environ Int. 2009;35(3):545-51.
Palma, P., Kuster, M., Alvarenga, P., Palma, V. L., Fernandes, R. M., Soares, A. M., López de Alda, M. J., Barceló, D., & Barbosa, I. R. (2009). Risk assessment of representative and priority pesticides, in surface water of the Alqueva reservoir (South of Portugal) using on-line solid phase extraction-liquid chromatography-tandem mass spectrometry. Environment International, 35(3), 545-51. https://doi.org/10.1016/j.envint.2008.09.015
Palma P, et al. Risk Assessment of Representative and Priority Pesticides, in Surface Water of the Alqueva Reservoir (South of Portugal) Using On-line Solid Phase Extraction-liquid Chromatography-tandem Mass Spectrometry. Environ Int. 2009;35(3):545-51. PubMed PMID: 19010545.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Risk assessment of representative and priority pesticides, in surface water of the Alqueva reservoir (South of Portugal) using on-line solid phase extraction-liquid chromatography-tandem mass spectrometry. AU - Palma,P, AU - Kuster,M, AU - Alvarenga,P, AU - Palma,V L, AU - Fernandes,R M, AU - Soares,A M V M, AU - López de Alda,M J, AU - Barceló,D, AU - Barbosa,I R, Y1 - 2008/11/17/ PY - 2008/07/15/received PY - 2008/09/24/revised PY - 2008/09/30/accepted PY - 2008/11/18/pubmed PY - 2009/4/8/medline PY - 2008/11/18/entrez SP - 545 EP - 51 JF - Environment international JO - Environ Int VL - 35 IS - 3 N2 - Surface waters located in intensive agricultural areas are more vulnerable to the pesticides contamination, which is a major concern if the water is intended to be used for human consumption. The aim of this study was to evaluate the presence and the distribution of pesticides in the Alqueva reservoir, an important source of water supply (South of Portugal), considering their representativeness in the agricultural practice of the area. For the analysis of pesticides risk impact we used the environmental quality standards in the field of water policy proposed recently by the European Commission. The pesticides belonging to the classes of phenylureas, triazines, chloroacetanilides, organophosphorous and thiocarbamates were analysed by on-line solid phase extraction-liquid chromatography-tandem mass spectrometry. The pesticides more frequently detected were atrazine, simazine, diuron and terbuthylazine. The highest levels of these pesticides were registered in spring, after pesticides treatment, namely in olive-tree and vine crops. The priority pesticides atrazine and diuron reached values above the annual average proposed in the European Union Legislation. The herbicide atrazine reached values that surpassed the proposed maximum allowable concentration (2,000 ng L(-1)). The sampling stations most affected by these pesticides were Sra. Ajuda, Lucefecit and Alcarrache, located in the northern part of the reservoir, closer to Spain where the agricultural activity is more intensive. SN - 1873-6750 UR - https://www.unboundmedicine.com/medline/citation/19010545/Risk_assessment_of_representative_and_priority_pesticides_in_surface_water_of_the_Alqueva_reservoir__South_of_Portugal__using_on_line_solid_phase_extraction_liquid_chromatography_tandem_mass_spectrometry_ L2 - https://linkinghub.elsevier.com/retrieve/pii/S0160-4120(08)00214-6 DB - PRIME DP - Unbound Medicine ER -