Tags

Type your tag names separated by a space and hit enter

Highly enantioselective 1,3-dipolar cycloaddition of azomethine ylides catalyzed by copper(I)/TF-BiphamPhos complexes.
J Am Chem Soc. 2008 Dec 24; 130(51):17250-1.JA

Abstract

A new and highly efficient Cu(I)/TF-BiphamPhos catalytic system exhibited excellent reactivity, enantio-/diastereoselectivity, and structural scope in asymmetric 1,3-dipolar cycloaddition of azomethine ylides with 0.1-3 mol % of catalyst loading. The present methodology is the best result for asymmetric cycloaddition of azomethine ylides, especially derived from amino esters other than glycinate in terms of reactivity and enantioselectivity.

Links

Publisher Full Text (DOI)

Authors+Show Affiliations

Wang CJ
College of Chemistry and Molecular Sciences, Wuhan University, PR China 430072. cjwang@whu.edu.cn
Liang G
No affiliation info available
Xue ZY
No affiliation info available
Gao F
No affiliation info available

MeSH

Amino AcidsAzo CompoundsCatalysisChemistryCopperMacromolecular SubstancesModels, ChemicalMolecular StructureNitrogenStereoisomerismTemperatureThiosemicarbazones

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

19035782

Citation

Wang, Chun-Jiang, et al. "Highly Enantioselective 1,3-dipolar Cycloaddition of Azomethine Ylides Catalyzed By copper(I)/TF-BiphamPhos Complexes." Journal of the American Chemical Society, vol. 130, no. 51, 2008, pp. 17250-1.
Wang CJ, Liang G, Xue ZY, et al. Highly enantioselective 1,3-dipolar cycloaddition of azomethine ylides catalyzed by copper(I)/TF-BiphamPhos complexes. J Am Chem Soc. 2008;130(51):17250-1.
Wang, C. J., Liang, G., Xue, Z. Y., & Gao, F. (2008). Highly enantioselective 1,3-dipolar cycloaddition of azomethine ylides catalyzed by copper(I)/TF-BiphamPhos complexes. Journal of the American Chemical Society, 130(51), 17250-1. https://doi.org/10.1021/ja807669q
Wang CJ, et al. Highly Enantioselective 1,3-dipolar Cycloaddition of Azomethine Ylides Catalyzed By copper(I)/TF-BiphamPhos Complexes. J Am Chem Soc. 2008 Dec 24;130(51):17250-1. PubMed PMID: 19035782.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Highly enantioselective 1,3-dipolar cycloaddition of azomethine ylides catalyzed by copper(I)/TF-BiphamPhos complexes. AU - Wang,Chun-Jiang, AU - Liang,Gang, AU - Xue,Zhi-Yong, AU - Gao,Feng, PY - 2008/11/28/pubmed PY - 2009/8/6/medline PY - 2008/11/28/entrez SP - 17250 EP - 1 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 130 IS - 51 N2 - A new and highly efficient Cu(I)/TF-BiphamPhos catalytic system exhibited excellent reactivity, enantio-/diastereoselectivity, and structural scope in asymmetric 1,3-dipolar cycloaddition of azomethine ylides with 0.1-3 mol % of catalyst loading. The present methodology is the best result for asymmetric cycloaddition of azomethine ylides, especially derived from amino esters other than glycinate in terms of reactivity and enantioselectivity. SN - 1520-5126 UR - https://www.unboundmedicine.com/medline/citation/19035782/Highly_enantioselective_13_dipolar_cycloaddition_of_azomethine_ylides_catalyzed_by_copper_I_/TF_BiphamPhos_complexes_ L2 - https://doi.org/10.1021/ja807669q DB - PRIME DP - Unbound Medicine ER -