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Highly regioselective hydroformylation of styrene and its derivatives catalyzed by Rh complex with tetraphosphorus ligands.
Org Lett. 2009 Jan 01; 11(1):241-4.OL

Abstract

Styrene has been hydroformylated to the linear aldehyde with surprisingly high regioselectivity (l/b up to 22 for styrene) by using Rh complex with tetraphosphorus ligand. To the best of our knowledge, this is the highest linear regioselectivity reported for the hydroformylation of styrene and its derivatives. This protocol is in sharp contrast to other processes that favor producing branched aldehyde (typically >95% branched for most bidentate systems).

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Publisher Full Text (DOI)

Authors+Show Affiliations

Yu S
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854-8020, USA.
Chie YM
No affiliation info available
Guan ZH
No affiliation info available
Zou Y
No affiliation info available
Li W
No affiliation info available
Zhang X
No affiliation info available

MeSH

AldehydesCatalysisLigandsMolecular StructureOrganometallic CompoundsOrganophosphorus CompoundsRhodiumStereoisomerismStyrenes

Pub Type(s)

Journal Article
Research Support, N.I.H., Extramural
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

19053715

Citation

Yu, Shichao, et al. "Highly Regioselective Hydroformylation of Styrene and Its Derivatives Catalyzed By Rh Complex With Tetraphosphorus Ligands." Organic Letters, vol. 11, no. 1, 2009, pp. 241-4.
Yu S, Chie YM, Guan ZH, et al. Highly regioselective hydroformylation of styrene and its derivatives catalyzed by Rh complex with tetraphosphorus ligands. Org Lett. 2009;11(1):241-4.
Yu, S., Chie, Y. M., Guan, Z. H., Zou, Y., Li, W., & Zhang, X. (2009). Highly regioselective hydroformylation of styrene and its derivatives catalyzed by Rh complex with tetraphosphorus ligands. Organic Letters, 11(1), 241-4. https://doi.org/10.1021/ol802479y
Yu S, et al. Highly Regioselective Hydroformylation of Styrene and Its Derivatives Catalyzed By Rh Complex With Tetraphosphorus Ligands. Org Lett. 2009 Jan 1;11(1):241-4. PubMed PMID: 19053715.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Highly regioselective hydroformylation of styrene and its derivatives catalyzed by Rh complex with tetraphosphorus ligands. AU - Yu,Shichao, AU - Chie,Yu-ming, AU - Guan,Zheng-hui, AU - Zou,Yaping, AU - Li,Wei, AU - Zhang,Xumu, PY - 2008/12/5/pubmed PY - 2009/2/12/medline PY - 2008/12/5/entrez SP - 241 EP - 4 JF - Organic letters JO - Org Lett VL - 11 IS - 1 N2 - Styrene has been hydroformylated to the linear aldehyde with surprisingly high regioselectivity (l/b up to 22 for styrene) by using Rh complex with tetraphosphorus ligand. To the best of our knowledge, this is the highest linear regioselectivity reported for the hydroformylation of styrene and its derivatives. This protocol is in sharp contrast to other processes that favor producing branched aldehyde (typically >95% branched for most bidentate systems). SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/19053715/Highly_regioselective_hydroformylation_of_styrene_and_its_derivatives_catalyzed_by_Rh_complex_with_tetraphosphorus_ligands_ L2 - https://doi.org/10.1021/ol802479y DB - PRIME DP - Unbound Medicine ER -