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Comparative analysis of the volatile fraction from Annona cherimola Mill. cultivars by solid-phase microextraction and gas chromatography-quadrupole mass spectrometry detection.
Talanta. 2009 Jan 15; 77(3):1087-96.T

Abstract

The analysis of volatile compounds in Funchal, Madeira, Mateus and Perry Vidal cultivars of Annona cherimola Mill. (cherimoya) was carried out by headspace solid-phase microextraction (HS-SPME) combined with gas chromatography-quadrupole mass spectrometry detection (GC-qMSD). HS-SPME technique was optimized in terms of fibre selection, extraction time, extraction temperature and sample amount to reach the best extraction efficiency. The best result was obtained with 2g of sample, using a divinylbenzene/carboxen/polydimethylsiloxane (DVB/CAR/PDMS) fibre for 30 min at 30 degrees C under constant magnetic stirring (800 rpm). After optimization of the extraction methodology, all the cherimoya samples were analysed with the best conditions that allowed to identify about 60 volatile compounds. The major compounds identified in the four cherimoya cultivars were methyl butanoate, butyl butanoate, 3-methylbutyl butanoate, 3-methylbutyl 3-methylbutanoate and 5-hydroxymethyl-2-furfural. These compounds represent 69.08+/-5.22%, 56.56+/-15.36%, 56.69+/-9.28% and 71.82+/-1.29% of the total volatiles for Funchal, Madeira, Mateus and Perry Vidal cultivars, respectively. This study showed that each cherimoya cultivars have 40 common compounds, corresponding to different chemical families, namely terpenes, esters, alcohols, fatty acids and carbonyl compounds and using PCA, the volatile composition in terms of average peak areas, provided a suitable tool to differentiate among the cherimoya cultivars.

Authors+Show Affiliations

Departamento de Química, Universidade da Madeira, Centro de Química da Madeira, Funchal, Portugal.No affiliation info availableNo affiliation info available

Pub Type(s)

Comparative Study
Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

19064096

Citation

Ferreira, Liseth, et al. "Comparative Analysis of the Volatile Fraction From Annona Cherimola Mill. Cultivars By Solid-phase Microextraction and Gas Chromatography-quadrupole Mass Spectrometry Detection." Talanta, vol. 77, no. 3, 2009, pp. 1087-96.
Ferreira L, Perestrelo R, Câmara JS. Comparative analysis of the volatile fraction from Annona cherimola Mill. cultivars by solid-phase microextraction and gas chromatography-quadrupole mass spectrometry detection. Talanta. 2009;77(3):1087-96.
Ferreira, L., Perestrelo, R., & Câmara, J. S. (2009). Comparative analysis of the volatile fraction from Annona cherimola Mill. cultivars by solid-phase microextraction and gas chromatography-quadrupole mass spectrometry detection. Talanta, 77(3), 1087-96. https://doi.org/10.1016/j.talanta.2008.08.011
Ferreira L, Perestrelo R, Câmara JS. Comparative Analysis of the Volatile Fraction From Annona Cherimola Mill. Cultivars By Solid-phase Microextraction and Gas Chromatography-quadrupole Mass Spectrometry Detection. Talanta. 2009 Jan 15;77(3):1087-96. PubMed PMID: 19064096.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Comparative analysis of the volatile fraction from Annona cherimola Mill. cultivars by solid-phase microextraction and gas chromatography-quadrupole mass spectrometry detection. AU - Ferreira,Liseth, AU - Perestrelo,Rosa, AU - Câmara,J S, Y1 - 2008/08/26/ PY - 2008/02/20/received PY - 2008/07/28/revised PY - 2008/08/18/accepted PY - 2008/12/10/pubmed PY - 2009/1/24/medline PY - 2008/12/10/entrez SP - 1087 EP - 96 JF - Talanta JO - Talanta VL - 77 IS - 3 N2 - The analysis of volatile compounds in Funchal, Madeira, Mateus and Perry Vidal cultivars of Annona cherimola Mill. (cherimoya) was carried out by headspace solid-phase microextraction (HS-SPME) combined with gas chromatography-quadrupole mass spectrometry detection (GC-qMSD). HS-SPME technique was optimized in terms of fibre selection, extraction time, extraction temperature and sample amount to reach the best extraction efficiency. The best result was obtained with 2g of sample, using a divinylbenzene/carboxen/polydimethylsiloxane (DVB/CAR/PDMS) fibre for 30 min at 30 degrees C under constant magnetic stirring (800 rpm). After optimization of the extraction methodology, all the cherimoya samples were analysed with the best conditions that allowed to identify about 60 volatile compounds. The major compounds identified in the four cherimoya cultivars were methyl butanoate, butyl butanoate, 3-methylbutyl butanoate, 3-methylbutyl 3-methylbutanoate and 5-hydroxymethyl-2-furfural. These compounds represent 69.08+/-5.22%, 56.56+/-15.36%, 56.69+/-9.28% and 71.82+/-1.29% of the total volatiles for Funchal, Madeira, Mateus and Perry Vidal cultivars, respectively. This study showed that each cherimoya cultivars have 40 common compounds, corresponding to different chemical families, namely terpenes, esters, alcohols, fatty acids and carbonyl compounds and using PCA, the volatile composition in terms of average peak areas, provided a suitable tool to differentiate among the cherimoya cultivars. SN - 1873-3573 UR - https://www.unboundmedicine.com/medline/citation/19064096/Comparative_analysis_of_the_volatile_fraction_from_Annona_cherimola_Mill__cultivars_by_solid_phase_microextraction_and_gas_chromatography_quadrupole_mass_spectrometry_detection_ L2 - https://linkinghub.elsevier.com/retrieve/pii/S0039-9140(08)00616-4 DB - PRIME DP - Unbound Medicine ER -