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Palladium-catalyzed cross coupling reaction of benzyl bromides with diazoesters for stereoselective synthesis of (E)-alpha,beta-diarylacrylates.
Org Lett. 2009 Jan 15; 11(2):469-72.OL

Abstract

A Pd-catalyzed cross-coupling reaction of benzyl bromides with alpha-aryldiazoesters is described, and E-alpha,beta-diarylacrylates were obtained in good yields and excellent E-to-Z selectivity (>20:1).

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Publisher Full Text (DOI)

Authors+Show Affiliations

Yu WY
Department of Applied Biology and Chemical Technology and Open Laboratory of Chirotechnology, Institute of Molecular Technology for Drug Discovery and Synthesis, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong. bcwyyu@inet.polyu.edu.hk
Tsoi YT
No affiliation info available
Zhou Z
No affiliation info available
Chan AS
No affiliation info available

MeSH

AcrylatesAlkenesAzo CompoundsBenzyl CompoundsCatalysisPalladiumStereoisomerismSubstrate Specificity

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

19099492

Citation

Yu, Wing-Yiu, et al. "Palladium-catalyzed Cross Coupling Reaction of Benzyl Bromides With Diazoesters for Stereoselective Synthesis of (E)-alpha,beta-diarylacrylates." Organic Letters, vol. 11, no. 2, 2009, pp. 469-72.
Yu WY, Tsoi YT, Zhou Z, et al. Palladium-catalyzed cross coupling reaction of benzyl bromides with diazoesters for stereoselective synthesis of (E)-alpha,beta-diarylacrylates. Org Lett. 2009;11(2):469-72.
Yu, W. Y., Tsoi, Y. T., Zhou, Z., & Chan, A. S. (2009). Palladium-catalyzed cross coupling reaction of benzyl bromides with diazoesters for stereoselective synthesis of (E)-alpha,beta-diarylacrylates. Organic Letters, 11(2), 469-72. https://doi.org/10.1021/ol8026076
Yu WY, et al. Palladium-catalyzed Cross Coupling Reaction of Benzyl Bromides With Diazoesters for Stereoselective Synthesis of (E)-alpha,beta-diarylacrylates. Org Lett. 2009 Jan 15;11(2):469-72. PubMed PMID: 19099492.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Palladium-catalyzed cross coupling reaction of benzyl bromides with diazoesters for stereoselective synthesis of (E)-alpha,beta-diarylacrylates. AU - Yu,Wing-Yiu, AU - Tsoi,Yuk-Tai, AU - Zhou,Zhongyuan, AU - Chan,Albert S C, PY - 2008/12/23/entrez PY - 2008/12/23/pubmed PY - 2009/3/5/medline SP - 469 EP - 72 JF - Organic letters JO - Org Lett VL - 11 IS - 2 N2 - A Pd-catalyzed cross-coupling reaction of benzyl bromides with alpha-aryldiazoesters is described, and E-alpha,beta-diarylacrylates were obtained in good yields and excellent E-to-Z selectivity (>20:1). SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/19099492/Palladium_catalyzed_cross_coupling_reaction_of_benzyl_bromides_with_diazoesters_for_stereoselective_synthesis_of__E__alphabeta_diarylacrylates_ L2 - https://doi.org/10.1021/ol8026076 DB - PRIME DP - Unbound Medicine ER -