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Preparation of solid-phase microextraction fiber coated with single-walled carbon nanotubes by electrophoretic deposition and its application in extracting phenols from aqueous samples.
J Chromatogr A. 2009 Feb 27; 1216(9):1305-11.JC

Abstract

A novel solid-phase microextraction (SPME) Pt fiber coated with single-walled carbon nanotubes (SWCNTs) was prepared by electrophoretic deposition (EPD) and applied to the determination of phenols in aqueous samples by direct immersion (DI)-SPME-HPLC-UV. The results revealed that EPD was a simple and reproducible technique for the preparation of SPME fibers coated with SWCNTs without the use of adhesive. The obtained SWCNT coating did not swell in organic solvents nor strip off from substrate, and possessed high mechanical strength due to the strong Van der Waals attractions between the surfaces of the SWCNTs. The prepared SPME fiber was conductive since both SWCNT coating and Pt wire were conductive. Using Pt wire as substrate, the fiber was unbreakable. Owing to the presence of oxygenated groups on SWCNTs and the high surface area of SWCNTs, the SWCNT fiber was similar to or superior to commercial PA fiber in extracting the studied phenols from aqueous sample. A durability of more than 80 analyses was achieved for one unique fiber. Under optimized conditions, the detection limits for the phenols varied between 0.9 and 3.8 ng/mL, the precisions were in the range of 0.7-3.2% (n=3), and linear ranges were within 10 and 300 ng/mL. The method was successfully applied to the analysis of spiked seawater and tap water samples with the recoveries from 87.5 to 102.0%.

Authors+Show Affiliations

State Key Laboratory of Marine Environmental Science, Environmental Science Research Center, Xiamen University, Xiamen 361005, China. liql@xmu.edu.cnNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

19162268

Citation

Li, Quanlong, et al. "Preparation of Solid-phase Microextraction Fiber Coated With Single-walled Carbon Nanotubes By Electrophoretic Deposition and Its Application in Extracting Phenols From Aqueous Samples." Journal of Chromatography. A, vol. 1216, no. 9, 2009, pp. 1305-11.
Li Q, Wang X, Yuan D. Preparation of solid-phase microextraction fiber coated with single-walled carbon nanotubes by electrophoretic deposition and its application in extracting phenols from aqueous samples. J Chromatogr A. 2009;1216(9):1305-11.
Li, Q., Wang, X., & Yuan, D. (2009). Preparation of solid-phase microextraction fiber coated with single-walled carbon nanotubes by electrophoretic deposition and its application in extracting phenols from aqueous samples. Journal of Chromatography. A, 1216(9), 1305-11. https://doi.org/10.1016/j.chroma.2008.12.082
Li Q, Wang X, Yuan D. Preparation of Solid-phase Microextraction Fiber Coated With Single-walled Carbon Nanotubes By Electrophoretic Deposition and Its Application in Extracting Phenols From Aqueous Samples. J Chromatogr A. 2009 Feb 27;1216(9):1305-11. PubMed PMID: 19162268.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Preparation of solid-phase microextraction fiber coated with single-walled carbon nanotubes by electrophoretic deposition and its application in extracting phenols from aqueous samples. AU - Li,Quanlong, AU - Wang,Xuefeng, AU - Yuan,Dongxing, Y1 - 2009/01/06/ PY - 2008/11/06/received PY - 2008/12/21/revised PY - 2008/12/29/accepted PY - 2009/1/24/entrez PY - 2009/1/24/pubmed PY - 2009/5/1/medline SP - 1305 EP - 11 JF - Journal of chromatography. A JO - J Chromatogr A VL - 1216 IS - 9 N2 - A novel solid-phase microextraction (SPME) Pt fiber coated with single-walled carbon nanotubes (SWCNTs) was prepared by electrophoretic deposition (EPD) and applied to the determination of phenols in aqueous samples by direct immersion (DI)-SPME-HPLC-UV. The results revealed that EPD was a simple and reproducible technique for the preparation of SPME fibers coated with SWCNTs without the use of adhesive. The obtained SWCNT coating did not swell in organic solvents nor strip off from substrate, and possessed high mechanical strength due to the strong Van der Waals attractions between the surfaces of the SWCNTs. The prepared SPME fiber was conductive since both SWCNT coating and Pt wire were conductive. Using Pt wire as substrate, the fiber was unbreakable. Owing to the presence of oxygenated groups on SWCNTs and the high surface area of SWCNTs, the SWCNT fiber was similar to or superior to commercial PA fiber in extracting the studied phenols from aqueous sample. A durability of more than 80 analyses was achieved for one unique fiber. Under optimized conditions, the detection limits for the phenols varied between 0.9 and 3.8 ng/mL, the precisions were in the range of 0.7-3.2% (n=3), and linear ranges were within 10 and 300 ng/mL. The method was successfully applied to the analysis of spiked seawater and tap water samples with the recoveries from 87.5 to 102.0%. SN - 1873-3778 UR - https://www.unboundmedicine.com/medline/citation/19162268/Preparation_of_solid_phase_microextraction_fiber_coated_with_single_walled_carbon_nanotubes_by_electrophoretic_deposition_and_its_application_in_extracting_phenols_from_aqueous_samples_ L2 - https://linkinghub.elsevier.com/retrieve/pii/S0021-9673(09)00003-X DB - PRIME DP - Unbound Medicine ER -