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Iron-catalyzed asymmetric aerobic oxidation: oxidative coupling of 2-naphthols.
J Am Chem Soc. 2009 May 06; 131(17):6082-3.JA

Abstract

Fe(salan) complexes were found to be efficient catalysts for the asymmetric aerobic oxidative coupling of 2-naphthol derivatives. This reaction can be carried out in air at 60 degrees C with high enantioselectivity up to 97% ee. This is the first report for asymmetric aerobic oxidation using molecular oxygen in air in the absence of additives.

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Authors+Show Affiliations

Egami H
Department of Chemistry, Faculty of Science, Graduate School, Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan.
Katsuki T
No affiliation info available

MeSH

CatalysisFerric CompoundsMolecular ConformationNaphtholsOxidation-ReductionOxygen

Pub Type(s)

Journal Article

Language

eng

PubMed ID

19361160

Citation

Egami, Hiromichi, and Tsutomu Katsuki. "Iron-catalyzed Asymmetric Aerobic Oxidation: Oxidative Coupling of 2-naphthols." Journal of the American Chemical Society, vol. 131, no. 17, 2009, pp. 6082-3.
Egami H, Katsuki T. Iron-catalyzed asymmetric aerobic oxidation: oxidative coupling of 2-naphthols. J Am Chem Soc. 2009;131(17):6082-3.
Egami, H., & Katsuki, T. (2009). Iron-catalyzed asymmetric aerobic oxidation: oxidative coupling of 2-naphthols. Journal of the American Chemical Society, 131(17), 6082-3. https://doi.org/10.1021/ja901391u
Egami H, Katsuki T. Iron-catalyzed Asymmetric Aerobic Oxidation: Oxidative Coupling of 2-naphthols. J Am Chem Soc. 2009 May 6;131(17):6082-3. PubMed PMID: 19361160.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Iron-catalyzed asymmetric aerobic oxidation: oxidative coupling of 2-naphthols. AU - Egami,Hiromichi, AU - Katsuki,Tsutomu, PY - 2009/4/14/entrez PY - 2009/4/14/pubmed PY - 2009/7/2/medline SP - 6082 EP - 3 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 131 IS - 17 N2 - Fe(salan) complexes were found to be efficient catalysts for the asymmetric aerobic oxidative coupling of 2-naphthol derivatives. This reaction can be carried out in air at 60 degrees C with high enantioselectivity up to 97% ee. This is the first report for asymmetric aerobic oxidation using molecular oxygen in air in the absence of additives. SN - 1520-5126 UR - https://www.unboundmedicine.com/medline/citation/19361160/Iron_catalyzed_asymmetric_aerobic_oxidation:_oxidative_coupling_of_2_naphthols_ L2 - https://doi.org/10.1021/ja901391u DB - PRIME DP - Unbound Medicine ER -