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A method for benzoyl chloride derivatization of biogenic amines for high performance liquid chromatography.
Talanta. 2009 Jun 15; 78(4-5):1321-6.T

Abstract

A new benzoylation procedure was developed which was more reliable than the most common benzoylation procedures in terms of reaction time, peak resolution, detector response and repeatability. Methylamine, putrescine, cadaverine, tryptamine, beta-phenylethylamine, spermidine, spermine, histamine, tyramine and agmatine were studied. Linearity for each biogenic amine was observed with a good regression coefficient. Limits of detection were found between 0.2mg/l and 2.5mg/l. Recovery rates varied from 72.8% to 103.4%. Temperature and pH of mobile phase were studied and found that 20 degrees C of column temperature with a pH of 8 was preferable. It was established that polyvinylpyrrolidone adsorbed biogenic amines and caused interference in HPLC determination of biogenic amines that had been used by some authors to eliminate interfering phenolic compounds in wine samples.

Authors+Show Affiliations

Ege University, Food Engineering Department, 35100 Bornova Izmir, Turkey. ozgul.ozdestan@ege.edu.trNo affiliation info available

Pub Type(s)

Evaluation Study
Journal Article

Language

eng

PubMed ID

19362195

Citation

Ozdestan, Ozgül, and Ali Uren. "A Method for Benzoyl Chloride Derivatization of Biogenic Amines for High Performance Liquid Chromatography." Talanta, vol. 78, no. 4-5, 2009, pp. 1321-6.
Ozdestan O, Uren A. A method for benzoyl chloride derivatization of biogenic amines for high performance liquid chromatography. Talanta. 2009;78(4-5):1321-6.
Ozdestan, O., & Uren, A. (2009). A method for benzoyl chloride derivatization of biogenic amines for high performance liquid chromatography. Talanta, 78(4-5), 1321-6. https://doi.org/10.1016/j.talanta.2009.02.001
Ozdestan O, Uren A. A Method for Benzoyl Chloride Derivatization of Biogenic Amines for High Performance Liquid Chromatography. Talanta. 2009 Jun 15;78(4-5):1321-6. PubMed PMID: 19362195.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - A method for benzoyl chloride derivatization of biogenic amines for high performance liquid chromatography. AU - Ozdestan,Ozgül, AU - Uren,Ali, Y1 - 2009/02/10/ PY - 2008/11/07/received PY - 2009/01/26/revised PY - 2009/02/02/accepted PY - 2009/4/14/entrez PY - 2009/4/14/pubmed PY - 2009/7/31/medline SP - 1321 EP - 6 JF - Talanta JO - Talanta VL - 78 IS - 4-5 N2 - A new benzoylation procedure was developed which was more reliable than the most common benzoylation procedures in terms of reaction time, peak resolution, detector response and repeatability. Methylamine, putrescine, cadaverine, tryptamine, beta-phenylethylamine, spermidine, spermine, histamine, tyramine and agmatine were studied. Linearity for each biogenic amine was observed with a good regression coefficient. Limits of detection were found between 0.2mg/l and 2.5mg/l. Recovery rates varied from 72.8% to 103.4%. Temperature and pH of mobile phase were studied and found that 20 degrees C of column temperature with a pH of 8 was preferable. It was established that polyvinylpyrrolidone adsorbed biogenic amines and caused interference in HPLC determination of biogenic amines that had been used by some authors to eliminate interfering phenolic compounds in wine samples. SN - 1873-3573 UR - https://www.unboundmedicine.com/medline/citation/19362195/A_method_for_benzoyl_chloride_derivatization_of_biogenic_amines_for_high_performance_liquid_chromatography_ L2 - https://linkinghub.elsevier.com/retrieve/pii/S0039-9140(09)00130-1 DB - PRIME DP - Unbound Medicine ER -