Platinum(II)-catalyzed intramolecular cyclization of o-substituted aryl alkynes through sp3 C-H activation.Angew Chem Int Ed Engl. 2009; 48(22):3999-4001.AC
Abstract
Ring leader: PtCl(2) catalyzes intramolecular cyclization of o-isopropyl or o-benzyl aryl alkynes to give substituted indene derivatives with good yields and high selectivity. This reaction appears to proceed through an sp(3) C-H activation and 1,4-hydrogen migration pathway (see scheme).
Links
Pub Type(s)
Journal Article
Research Support, Non-U.S. Gov't
Language
eng
PubMed ID
19402084
Citation
Yang, Shangdong, et al. "Platinum(II)-catalyzed Intramolecular Cyclization of O-substituted Aryl Alkynes Through Sp3 C-H Activation." Angewandte Chemie (International Ed. in English), vol. 48, no. 22, 2009, pp. 3999-4001.
Yang S, Li Z, Jian X, et al. Platinum(II)-catalyzed intramolecular cyclization of o-substituted aryl alkynes through sp3 C-H activation. Angew Chem Int Ed Engl. 2009;48(22):3999-4001.
Yang, S., Li, Z., Jian, X., & He, C. (2009). Platinum(II)-catalyzed intramolecular cyclization of o-substituted aryl alkynes through sp3 C-H activation. Angewandte Chemie (International Ed. in English), 48(22), 3999-4001. https://doi.org/10.1002/anie.200900368
Yang S, et al. Platinum(II)-catalyzed Intramolecular Cyclization of O-substituted Aryl Alkynes Through Sp3 C-H Activation. Angew Chem Int Ed Engl. 2009;48(22):3999-4001. PubMed PMID: 19402084.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR
T1 - Platinum(II)-catalyzed intramolecular cyclization of o-substituted aryl alkynes through sp3 C-H activation.
AU - Yang,Shangdong,
AU - Li,Zigang,
AU - Jian,Xing,
AU - He,Chuan,
PY - 2009/4/30/entrez
PY - 2009/4/30/pubmed
PY - 2009/6/24/medline
SP - 3999
EP - 4001
JF - Angewandte Chemie (International ed. in English)
JO - Angew Chem Int Ed Engl
VL - 48
IS - 22
N2 - Ring leader: PtCl(2) catalyzes intramolecular cyclization of o-isopropyl or o-benzyl aryl alkynes to give substituted indene derivatives with good yields and high selectivity. This reaction appears to proceed through an sp(3) C-H activation and 1,4-hydrogen migration pathway (see scheme).
SN - 1521-3773
UR - https://www.unboundmedicine.com/medline/citation/19402084/Platinum_II__catalyzed_intramolecular_cyclization_of_o_substituted_aryl_alkynes_through_sp3_C_H_activation_
L2 - https://doi.org/10.1002/anie.200900368
DB - PRIME
DP - Unbound Medicine
ER -
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