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A highly enantioselective allylic amination reaction using a commercially available chiral rhodium catalyst: resolution of racemic allylic carbonates.
Org Lett. 2009 Jul 16; 11(14):3140-2.OL

Abstract

A novel method for the kinetic resolution of unsymmetrical acyclic allylic carbonates and the concurrent synthesis of enantioenriched secondary amines using a commercially available chiral catalyst is disclosed.

Links

Publisher Full Text (DOI)

Authors+Show Affiliations

Vrieze DC
Pfizer Global Research and Development, 2800 Plymouth Road, Ann Arbor, Michigan 48105, USA. derek.vrieze@pfizer.com
Hoge GS
No affiliation info available
Hoerter PZ
No affiliation info available
Van Haitsma JT
No affiliation info available
Samas BM
No affiliation info available

MeSH

Allyl CompoundsAminesCarbonatesCatalysisMolecular StructureRhodiumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

19527001

Citation

Vrieze, Derek C., et al. "A Highly Enantioselective Allylic Amination Reaction Using a Commercially Available Chiral Rhodium Catalyst: Resolution of Racemic Allylic Carbonates." Organic Letters, vol. 11, no. 14, 2009, pp. 3140-2.
Vrieze DC, Hoge GS, Hoerter PZ, et al. A highly enantioselective allylic amination reaction using a commercially available chiral rhodium catalyst: resolution of racemic allylic carbonates. Org Lett. 2009;11(14):3140-2.
Vrieze, D. C., Hoge, G. S., Hoerter, P. Z., Van Haitsma, J. T., & Samas, B. M. (2009). A highly enantioselective allylic amination reaction using a commercially available chiral rhodium catalyst: resolution of racemic allylic carbonates. Organic Letters, 11(14), 3140-2. https://doi.org/10.1021/ol901031b
Vrieze DC, et al. A Highly Enantioselective Allylic Amination Reaction Using a Commercially Available Chiral Rhodium Catalyst: Resolution of Racemic Allylic Carbonates. Org Lett. 2009 Jul 16;11(14):3140-2. PubMed PMID: 19527001.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - A highly enantioselective allylic amination reaction using a commercially available chiral rhodium catalyst: resolution of racemic allylic carbonates. AU - Vrieze,Derek C, AU - Hoge,Garrett S, AU - Hoerter,Perrine Z, AU - Van Haitsma,Jared T, AU - Samas,Brian M, PY - 2009/6/17/entrez PY - 2009/6/17/pubmed PY - 2009/8/14/medline SP - 3140 EP - 2 JF - Organic letters JO - Org Lett VL - 11 IS - 14 N2 - A novel method for the kinetic resolution of unsymmetrical acyclic allylic carbonates and the concurrent synthesis of enantioenriched secondary amines using a commercially available chiral catalyst is disclosed. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/19527001/A_highly_enantioselective_allylic_amination_reaction_using_a_commercially_available_chiral_rhodium_catalyst:_resolution_of_racemic_allylic_carbonates_ L2 - https://doi.org/10.1021/ol901031b DB - PRIME DP - Unbound Medicine ER -