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The key intermediate in the amination of saturated C-H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)(2) (Ar = 3,5-(CF(3))(2)C(6)H(3)).
Chem Commun (Camb). 2009 Jul 14CC

Abstract

The complex Ru(TPP)(NAr)(2) inserts a nitrene group into allylic and benzylic C-H bonds and is the key intermediate in the ruthenium porphyrin-catalyzed amination of hydrocarbons by aryl azides.

Authors+Show Affiliations

Dipartimento di Chimica Inorganica, Metallorganica e Analitica L Malatesta, Università di Milano and ISTM-CNR, Milano, Italy.No affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article

Language

eng

PubMed ID

19662263

Citation

Fantauzzi, Simone, et al. "The Key Intermediate in the Amination of Saturated C-H Bonds: Synthesis, X-ray Characterization and Catalytic Activity of Ru(TPP)(NAr)(2) (Ar = 3,5-(CF(3))(2)C(6)H(3))." Chemical Communications (Cambridge, England), 2009, pp. 3952-4.
Fantauzzi S, Gallo E, Caselli A, et al. The key intermediate in the amination of saturated C-H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)(2) (Ar = 3,5-(CF(3))(2)C(6)H(3)). Chem Commun (Camb). 2009.
Fantauzzi, S., Gallo, E., Caselli, A., Ragaini, F., Casati, N., Macchi, P., & Cenini, S. (2009). The key intermediate in the amination of saturated C-H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)(2) (Ar = 3,5-(CF(3))(2)C(6)H(3)). Chemical Communications (Cambridge, England), (26), 3952-4. https://doi.org/10.1039/b903238j
Fantauzzi S, et al. The Key Intermediate in the Amination of Saturated C-H Bonds: Synthesis, X-ray Characterization and Catalytic Activity of Ru(TPP)(NAr)(2) (Ar = 3,5-(CF(3))(2)C(6)H(3)). Chem Commun (Camb). 2009 Jul 14;(26)3952-4. PubMed PMID: 19662263.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - The key intermediate in the amination of saturated C-H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)(2) (Ar = 3,5-(CF(3))(2)C(6)H(3)). AU - Fantauzzi,Simone, AU - Gallo,Emma, AU - Caselli,Alessandro, AU - Ragaini,Fabio, AU - Casati,Nicola, AU - Macchi,Piero, AU - Cenini,Sergio, Y1 - 2009/05/29/ PY - 2009/8/8/entrez PY - 2009/8/8/pubmed PY - 2009/8/8/medline SP - 3952 EP - 4 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) IS - 26 N2 - The complex Ru(TPP)(NAr)(2) inserts a nitrene group into allylic and benzylic C-H bonds and is the key intermediate in the ruthenium porphyrin-catalyzed amination of hydrocarbons by aryl azides. SN - 1359-7345 UR - https://www.unboundmedicine.com/medline/citation/19662263/The_key_intermediate_in_the_amination_of_saturated_C_H_bonds:_synthesis_X_ray_characterization_and_catalytic_activity_of_Ru_TPP__NAr__2___Ar_=_35__CF_3___2_C_6_H_3___ L2 - https://doi.org/10.1039/b903238j DB - PRIME DP - Unbound Medicine ER -
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