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Haloanisole and halophenol contamination in Spanish aged red wines.

Abstract

This is the first study to be carried out on the incidence of halophenols and haloanisoles, including trichloroanisole, in aged red wines. A total of 966 red wines, aged for 6, 12 and 24 months in oak barrels and from different Spanish production areas, were analysed by stir bar sorptive extraction followed by gas chromatography/mass spectrometry (GC/MS). From the wines sampled, 155 (16.1%) were contaminated with one or several compounds, with 7.6, 6.9 and 1.5% corresponding to the 12- (aged-12), 6- (aged-6) and 24-month-aged (aged-24) wines, respectively. The most abundant compounds causing taint were 2,3,4,6-tetrachloroanisole and 2,4,6-trichloroanisol (6.8 and 5.3%, respectively). No 2,4,6-tribromophenol was found in any of the samples. Contamination with halo compounds was highest in samples from South-West Spain, followed by those from Northern Spain. The mean concentration for all compounds were always higher than their respective olfactory threshold, but none of these halo compounds represent a health hazard to humans through the consumption of commercial red aged wines.

Authors+Show Affiliations

Catedra de Quimica Agricola, ETSIA, Universidad de Castilla-La Mancha, Albacete, Spain.No affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article

Language

eng

PubMed ID

19680868

Citation

Copete, M L., et al. "Haloanisole and Halophenol Contamination in Spanish Aged Red Wines." Food Additives & Contaminants. Part A, Chemistry, Analysis, Control, Exposure & Risk Assessment, vol. 26, no. 1, 2009, pp. 32-8.
Copete ML, Zalacain A, Lorenzo C, et al. Haloanisole and halophenol contamination in Spanish aged red wines. Food Addit Contam Part A Chem Anal Control Expo Risk Assess. 2009;26(1):32-8.
Copete, M. L., Zalacain, A., Lorenzo, C., Carot, J. M., Esteve, M. D., Climent, M., & Salinas, M. R. (2009). Haloanisole and halophenol contamination in Spanish aged red wines. Food Additives & Contaminants. Part A, Chemistry, Analysis, Control, Exposure & Risk Assessment, 26(1), 32-8. https://doi.org/10.1080/02652030802273130
Copete ML, et al. Haloanisole and Halophenol Contamination in Spanish Aged Red Wines. Food Addit Contam Part A Chem Anal Control Expo Risk Assess. 2009;26(1):32-8. PubMed PMID: 19680868.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Haloanisole and halophenol contamination in Spanish aged red wines. AU - Copete,M L, AU - Zalacain,A, AU - Lorenzo,C, AU - Carot,J M, AU - Esteve,M D, AU - Climent,M, AU - Salinas,M R, PY - 2009/8/15/entrez PY - 2009/8/15/pubmed PY - 2010/1/22/medline SP - 32 EP - 8 JF - Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment JO - Food Addit Contam Part A Chem Anal Control Expo Risk Assess VL - 26 IS - 1 N2 - This is the first study to be carried out on the incidence of halophenols and haloanisoles, including trichloroanisole, in aged red wines. A total of 966 red wines, aged for 6, 12 and 24 months in oak barrels and from different Spanish production areas, were analysed by stir bar sorptive extraction followed by gas chromatography/mass spectrometry (GC/MS). From the wines sampled, 155 (16.1%) were contaminated with one or several compounds, with 7.6, 6.9 and 1.5% corresponding to the 12- (aged-12), 6- (aged-6) and 24-month-aged (aged-24) wines, respectively. The most abundant compounds causing taint were 2,3,4,6-tetrachloroanisole and 2,4,6-trichloroanisol (6.8 and 5.3%, respectively). No 2,4,6-tribromophenol was found in any of the samples. Contamination with halo compounds was highest in samples from South-West Spain, followed by those from Northern Spain. The mean concentration for all compounds were always higher than their respective olfactory threshold, but none of these halo compounds represent a health hazard to humans through the consumption of commercial red aged wines. SN - 1944-0057 UR - https://www.unboundmedicine.com/medline/citation/19680868/Haloanisole_and_halophenol_contamination_in_Spanish_aged_red_wines_ L2 - https://www.tandfonline.com/doi/full/10.1080/02652030802273130 DB - PRIME DP - Unbound Medicine ER -