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Copper-catalyzed enantioselective carbenoid insertion into S-H bonds.
Chem Commun (Camb). 2009 Sep 28CC

Abstract

An asymmetric carbenoid insertion into S-H bonds catalyzed by copper-chiral spiro bisoxazoline complexes has been developed, in which a series of alpha-mercaptoesters were produced in high yields with moderate to good enantioselectivities (up to 85% ee); this result represents the best enantioselectivity in the catalytic asymmetric carbenoid S-H bond insertion reaction.

Authors+Show Affiliations

State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China.No affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article

Language

eng

PubMed ID

19724785

Citation

Zhang, Yong-Zhen, et al. "Copper-catalyzed Enantioselective Carbenoid Insertion Into S-H Bonds." Chemical Communications (Cambridge, England), 2009, pp. 5362-4.
Zhang YZ, Zhu SF, Cai Y, et al. Copper-catalyzed enantioselective carbenoid insertion into S-H bonds. Chem Commun (Camb). 2009.
Zhang, Y. Z., Zhu, S. F., Cai, Y., Mao, H. X., & Zhou, Q. L. (2009). Copper-catalyzed enantioselective carbenoid insertion into S-H bonds. Chemical Communications (Cambridge, England), (36), 5362-4. https://doi.org/10.1039/b911670b
Zhang YZ, et al. Copper-catalyzed Enantioselective Carbenoid Insertion Into S-H Bonds. Chem Commun (Camb). 2009 Sep 28;(36)5362-4. PubMed PMID: 19724785.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Copper-catalyzed enantioselective carbenoid insertion into S-H bonds. AU - Zhang,Yong-Zhen, AU - Zhu,Shou-Fei, AU - Cai,Yan, AU - Mao,Hong-Xiang, AU - Zhou,Qi-Lin, Y1 - 2009/08/11/ PY - 2009/9/3/entrez PY - 2009/9/3/pubmed PY - 2009/9/3/medline SP - 5362 EP - 4 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) IS - 36 N2 - An asymmetric carbenoid insertion into S-H bonds catalyzed by copper-chiral spiro bisoxazoline complexes has been developed, in which a series of alpha-mercaptoesters were produced in high yields with moderate to good enantioselectivities (up to 85% ee); this result represents the best enantioselectivity in the catalytic asymmetric carbenoid S-H bond insertion reaction. SN - 1364-548X UR - https://www.unboundmedicine.com/medline/citation/19724785/Copper_catalyzed_enantioselective_carbenoid_insertion_into_S_H_bonds_ L2 - https://doi.org/10.1039/b911670b DB - PRIME DP - Unbound Medicine ER -
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