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Simple chiral chain dienes as ligands for Rh(I)-catalyzed conjugated additions.
Org Lett. 2009 Oct 15; 11(20):4744-7.OL

Abstract

This paper describes that a simple and readily available chain diene (3R,4R)-hexa-1,5-diene-3,4-diol (L1) was successfully utilized as a novel steering ligand for Rh(I)-catalyzed asymmetric conjugated additions. Encouraging yields and ee's have been achieved, which may provide a new and practical direction for designing chiral diene ligands in the future.

Authors+Show Affiliations

Beijing National Laboratory of Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.No affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article

Language

eng

PubMed ID

19761192

Citation

Hu, Xichao, et al. "Simple Chiral Chain Dienes as Ligands for Rh(I)-catalyzed Conjugated Additions." Organic Letters, vol. 11, no. 20, 2009, pp. 4744-7.
Hu X, Zhuang M, Cao Z, et al. Simple chiral chain dienes as ligands for Rh(I)-catalyzed conjugated additions. Org Lett. 2009;11(20):4744-7.
Hu, X., Zhuang, M., Cao, Z., & Du, H. (2009). Simple chiral chain dienes as ligands for Rh(I)-catalyzed conjugated additions. Organic Letters, 11(20), 4744-7. https://doi.org/10.1021/ol901949n
Hu X, et al. Simple Chiral Chain Dienes as Ligands for Rh(I)-catalyzed Conjugated Additions. Org Lett. 2009 Oct 15;11(20):4744-7. PubMed PMID: 19761192.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Simple chiral chain dienes as ligands for Rh(I)-catalyzed conjugated additions. AU - Hu,Xichao, AU - Zhuang,Minyang, AU - Cao,Ziping, AU - Du,Haifeng, PY - 2009/9/19/entrez PY - 2009/9/19/pubmed PY - 2009/9/19/medline SP - 4744 EP - 7 JF - Organic letters JO - Org Lett VL - 11 IS - 20 N2 - This paper describes that a simple and readily available chain diene (3R,4R)-hexa-1,5-diene-3,4-diol (L1) was successfully utilized as a novel steering ligand for Rh(I)-catalyzed asymmetric conjugated additions. Encouraging yields and ee's have been achieved, which may provide a new and practical direction for designing chiral diene ligands in the future. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/19761192/Simple_chiral_chain_dienes_as_ligands_for_Rh_I__catalyzed_conjugated_additions_ L2 - https://doi.org/10.1021/ol901949n DB - PRIME DP - Unbound Medicine ER -
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