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Cross-coupling of alkenyl/aryl carboxylates with Grignard reagent via Fe-catalyzed C-O bond activation.
J Am Chem Soc. 2009 Oct 21; 131(41):14656-7.JA

Abstract

Iron-catalyzed cross-coupling of alkenyl/aryl carboxylates with primary alkyl Grignard reagent was described. This reaction brought a new family of electrophiles to iron catalysis. The combination of an inexpensive carboxylate electrophile and an iron catalyst would generate ample advantages.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Li BJ
Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871, China.
Xu L
No affiliation info available
Wu ZH
No affiliation info available
Guan BT
No affiliation info available
Sun CL
No affiliation info available
Wang BQ
No affiliation info available
Shi ZJ
No affiliation info available

MeSH

AlkenesCarbonCarboxylic AcidsCatalysisIndicators and ReagentsIronOxygen

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

19788187

Citation

Li, Bi-Jie, et al. "Cross-coupling of Alkenyl/aryl Carboxylates With Grignard Reagent Via Fe-catalyzed C-O Bond Activation." Journal of the American Chemical Society, vol. 131, no. 41, 2009, pp. 14656-7.
Li BJ, Xu L, Wu ZH, et al. Cross-coupling of alkenyl/aryl carboxylates with Grignard reagent via Fe-catalyzed C-O bond activation. J Am Chem Soc. 2009;131(41):14656-7.
Li, B. J., Xu, L., Wu, Z. H., Guan, B. T., Sun, C. L., Wang, B. Q., & Shi, Z. J. (2009). Cross-coupling of alkenyl/aryl carboxylates with Grignard reagent via Fe-catalyzed C-O bond activation. Journal of the American Chemical Society, 131(41), 14656-7. https://doi.org/10.1021/ja907281f
Li BJ, et al. Cross-coupling of Alkenyl/aryl Carboxylates With Grignard Reagent Via Fe-catalyzed C-O Bond Activation. J Am Chem Soc. 2009 Oct 21;131(41):14656-7. PubMed PMID: 19788187.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Cross-coupling of alkenyl/aryl carboxylates with Grignard reagent via Fe-catalyzed C-O bond activation. AU - Li,Bi-Jie, AU - Xu,Li, AU - Wu,Zhen-Hua, AU - Guan,Bing-Tao, AU - Sun,Chang-Liang, AU - Wang,Bi-Qin, AU - Shi,Zhang-Jie, PY - 2009/10/1/entrez PY - 2009/10/1/pubmed PY - 2010/1/12/medline SP - 14656 EP - 7 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 131 IS - 41 N2 - Iron-catalyzed cross-coupling of alkenyl/aryl carboxylates with primary alkyl Grignard reagent was described. This reaction brought a new family of electrophiles to iron catalysis. The combination of an inexpensive carboxylate electrophile and an iron catalyst would generate ample advantages. SN - 1520-5126 UR - https://www.unboundmedicine.com/medline/citation/19788187/Cross_coupling_of_alkenyl/aryl_carboxylates_with_Grignard_reagent_via_Fe_catalyzed_C_O_bond_activation_ L2 - https://doi.org/10.1021/ja907281f DB - PRIME DP - Unbound Medicine ER -