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Cationic rhodium(I)/bisphosphine complex-catalyzed cyclization of 1,6-diynes with carboxylic acids.
Org Biomol Chem. 2009 Dec 07; 7(23):4817-20.OB

Abstract

A cationic rhodium(I)/bisphosphine complex catalyzes carboxylative cyclizations of 1,6-diynes, leading to cyclic dienyl carboxylates, in high yields with high chemo-, regio-, and stereoselectivities under mild reaction conditions.

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Authors+Show Affiliations

Tanaka K
Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan. tanaka-k@cc.tuat.ac.jp
Saitoh S
No affiliation info available
Hara H
No affiliation info available
Shibata Y
No affiliation info available

MeSH

AlkynesCarboxylic AcidsCatalysisCationsCyclizationOrganometallic CompoundsPhosphinesRhodiumStereoisomerism

Pub Type(s)

Journal Article

Language

eng

PubMed ID

19907768

Citation

Tanaka, Ken, et al. "Cationic rhodium(I)/bisphosphine Complex-catalyzed Cyclization of 1,6-diynes With Carboxylic Acids." Organic & Biomolecular Chemistry, vol. 7, no. 23, 2009, pp. 4817-20.
Tanaka K, Saitoh S, Hara H, et al. Cationic rhodium(I)/bisphosphine complex-catalyzed cyclization of 1,6-diynes with carboxylic acids. Org Biomol Chem. 2009;7(23):4817-20.
Tanaka, K., Saitoh, S., Hara, H., & Shibata, Y. (2009). Cationic rhodium(I)/bisphosphine complex-catalyzed cyclization of 1,6-diynes with carboxylic acids. Organic & Biomolecular Chemistry, 7(23), 4817-20. https://doi.org/10.1039/b913344e
Tanaka K, et al. Cationic rhodium(I)/bisphosphine Complex-catalyzed Cyclization of 1,6-diynes With Carboxylic Acids. Org Biomol Chem. 2009 Dec 7;7(23):4817-20. PubMed PMID: 19907768.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Cationic rhodium(I)/bisphosphine complex-catalyzed cyclization of 1,6-diynes with carboxylic acids. AU - Tanaka,Ken, AU - Saitoh,Shunsuke, AU - Hara,Hiromi, AU - Shibata,Yu, Y1 - 2009/09/15/ PY - 2009/11/13/entrez PY - 2009/11/13/pubmed PY - 2010/2/13/medline SP - 4817 EP - 20 JF - Organic & biomolecular chemistry JO - Org Biomol Chem VL - 7 IS - 23 N2 - A cationic rhodium(I)/bisphosphine complex catalyzes carboxylative cyclizations of 1,6-diynes, leading to cyclic dienyl carboxylates, in high yields with high chemo-, regio-, and stereoselectivities under mild reaction conditions. SN - 1477-0539 UR - https://www.unboundmedicine.com/medline/citation/19907768/Cationic_rhodium_I_/bisphosphine_complex_catalyzed_cyclization_of_16_diynes_with_carboxylic_acids_ L2 - https://doi.org/10.1039/b913344e DB - PRIME DP - Unbound Medicine ER -