Tags

Type your tag names separated by a space and hit enter

Iridium-catalyzed, regio- and enantioselective allylic substitution with aromatic and aliphatic sulfinates.
Org Lett. 2010 Jan 01; 12(1):92-4.OL

Abstract

The iridium-catalyzed allylation of sodium sulfinate to form branched allylic sulfones is reported. The reactions between various sodium sulfinates and achiral allylic carbonates occur in good yields, with high selectivity for the branched isomer, and high enantioselectivities (up to 98% ee).

Links

PMC Free PDF
PMC Free Full Text

Authors+Show Affiliations

Ueda M
Department of Chemistry, University of Illinois, 600 South Matthews Avenue, Urbana, Illinois 61801, USA.
Hartwig JF
No affiliation info available

MeSH

Allyl CompoundsCatalysisIridiumStereoisomerismSulfinic AcidsSulfones

Pub Type(s)

Journal Article
Research Support, N.I.H., Extramural
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

19954200

Citation

Ueda, Mitsuhiro, and John F. Hartwig. "Iridium-catalyzed, Regio- and Enantioselective Allylic Substitution With Aromatic and Aliphatic Sulfinates." Organic Letters, vol. 12, no. 1, 2010, pp. 92-4.
Ueda M, Hartwig JF. Iridium-catalyzed, regio- and enantioselective allylic substitution with aromatic and aliphatic sulfinates. Org Lett. 2010;12(1):92-4.
Ueda, M., & Hartwig, J. F. (2010). Iridium-catalyzed, regio- and enantioselective allylic substitution with aromatic and aliphatic sulfinates. Organic Letters, 12(1), 92-4. https://doi.org/10.1021/ol9023248
Ueda M, Hartwig JF. Iridium-catalyzed, Regio- and Enantioselective Allylic Substitution With Aromatic and Aliphatic Sulfinates. Org Lett. 2010 Jan 1;12(1):92-4. PubMed PMID: 19954200.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Iridium-catalyzed, regio- and enantioselective allylic substitution with aromatic and aliphatic sulfinates. AU - Ueda,Mitsuhiro, AU - Hartwig,John F, PY - 2009/12/4/entrez PY - 2009/12/4/pubmed PY - 2010/2/24/medline SP - 92 EP - 4 JF - Organic letters JO - Org Lett VL - 12 IS - 1 N2 - The iridium-catalyzed allylation of sodium sulfinate to form branched allylic sulfones is reported. The reactions between various sodium sulfinates and achiral allylic carbonates occur in good yields, with high selectivity for the branched isomer, and high enantioselectivities (up to 98% ee). SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/19954200/Iridium_catalyzed_regio__and_enantioselective_allylic_substitution_with_aromatic_and_aliphatic_sulfinates_ L2 - https://doi.org/10.1021/ol9023248 DB - PRIME DP - Unbound Medicine ER -