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Catalytic asymmetric total synthesis of tangutorine.
Org Lett. 2010 Feb 19; 12(4):872-5.OL

Abstract

The first enantioselective total synthesis of tangutorine has been achieved, wherein a Pd-catalyzed asymmetric allylic amination using a chiral diaminophosphine oxide (DIAPHOX) preligand was the key step.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Nemoto T
Graduate School of Pharmaceutical Sciences, Chiba University, 1-33, Yayoi-cho, Inage-ku, Chiba 263-8522, Japan.
Yamamoto E
No affiliation info available
Franzén R
No affiliation info available
Fukuyama T
No affiliation info available
Wu R
No affiliation info available
Fukamachi T
No affiliation info available
Kobayashi H
No affiliation info available
Hamada Y
No affiliation info available

MeSH

Allyl CompoundsAminationCarbolinesCatalysisDrugs, Chinese HerbalMolecular StructurePalladiumQuinolizinesStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

20092264

Citation

Nemoto, Tetsuhiro, et al. "Catalytic Asymmetric Total Synthesis of Tangutorine." Organic Letters, vol. 12, no. 4, 2010, pp. 872-5.
Nemoto T, Yamamoto E, Franzén R, et al. Catalytic asymmetric total synthesis of tangutorine. Org Lett. 2010;12(4):872-5.
Nemoto, T., Yamamoto, E., Franzén, R., Fukuyama, T., Wu, R., Fukamachi, T., Kobayashi, H., & Hamada, Y. (2010). Catalytic asymmetric total synthesis of tangutorine. Organic Letters, 12(4), 872-5. https://doi.org/10.1021/ol902929a
Nemoto T, et al. Catalytic Asymmetric Total Synthesis of Tangutorine. Org Lett. 2010 Feb 19;12(4):872-5. PubMed PMID: 20092264.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Catalytic asymmetric total synthesis of tangutorine. AU - Nemoto,Tetsuhiro, AU - Yamamoto,Eri, AU - Franzén,Robert, AU - Fukuyama,Takashi, AU - Wu,Riliga, AU - Fukamachi,Toshihiko, AU - Kobayashi,Hiroshi, AU - Hamada,Yasumasa, PY - 2010/1/23/entrez PY - 2010/1/23/pubmed PY - 2010/3/12/medline SP - 872 EP - 5 JF - Organic letters JO - Org Lett VL - 12 IS - 4 N2 - The first enantioselective total synthesis of tangutorine has been achieved, wherein a Pd-catalyzed asymmetric allylic amination using a chiral diaminophosphine oxide (DIAPHOX) preligand was the key step. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/20092264/Catalytic_asymmetric_total_synthesis_of_tangutorine_ DB - PRIME DP - Unbound Medicine ER -