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Synthesis of naphtho[1,8-bc]pyran derivatives and related compounds through hydroxy group directed C-H bond cleavage under rhodium catalysis.
Chem Asian J. 2010 Apr 01; 5(4):847-51.CA

Abstract

The straightforward and efficient synthesis of naphtho[1,8-bc]pyran derivatives and related polycyclic compounds is achieved by the rhodium-catalyzed oxidative coupling of 1-naphthols or other phenolic and alcoholic substrates with alkynes. In these annulation reactions, the hydroxy groups effectively act as the key function for the regioselective C-H bond cleavage.

Authors+Show Affiliations

Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.No affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

20186908

Citation

Mochida, Satoshi, et al. "Synthesis of Naphtho[1,8-bc]pyran Derivatives and Related Compounds Through Hydroxy Group Directed C-H Bond Cleavage Under Rhodium Catalysis." Chemistry, an Asian Journal, vol. 5, no. 4, 2010, pp. 847-51.
Mochida S, Shimizu M, Hirano K, et al. Synthesis of naphtho[1,8-bc]pyran derivatives and related compounds through hydroxy group directed C-H bond cleavage under rhodium catalysis. Chem Asian J. 2010;5(4):847-51.
Mochida, S., Shimizu, M., Hirano, K., Satoh, T., & Miura, M. (2010). Synthesis of naphtho[1,8-bc]pyran derivatives and related compounds through hydroxy group directed C-H bond cleavage under rhodium catalysis. Chemistry, an Asian Journal, 5(4), 847-51. https://doi.org/10.1002/asia.200900639
Mochida S, et al. Synthesis of Naphtho[1,8-bc]pyran Derivatives and Related Compounds Through Hydroxy Group Directed C-H Bond Cleavage Under Rhodium Catalysis. Chem Asian J. 2010 Apr 1;5(4):847-51. PubMed PMID: 20186908.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Synthesis of naphtho[1,8-bc]pyran derivatives and related compounds through hydroxy group directed C-H bond cleavage under rhodium catalysis. AU - Mochida,Satoshi, AU - Shimizu,Masaki, AU - Hirano,Koji, AU - Satoh,Tetsuya, AU - Miura,Masahiro, PY - 2010/2/27/entrez PY - 2010/2/27/pubmed PY - 2010/7/9/medline SP - 847 EP - 51 JF - Chemistry, an Asian journal JO - Chem Asian J VL - 5 IS - 4 N2 - The straightforward and efficient synthesis of naphtho[1,8-bc]pyran derivatives and related polycyclic compounds is achieved by the rhodium-catalyzed oxidative coupling of 1-naphthols or other phenolic and alcoholic substrates with alkynes. In these annulation reactions, the hydroxy groups effectively act as the key function for the regioselective C-H bond cleavage. SN - 1861-471X UR - https://www.unboundmedicine.com/medline/citation/20186908/Synthesis_of_naphtho[18_bc]pyran_derivatives_and_related_compounds_through_hydroxy_group_directed_C_H_bond_cleavage_under_rhodium_catalysis_ L2 - https://doi.org/10.1002/asia.200900639 DB - PRIME DP - Unbound Medicine ER -