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Synthesis of 2-indolylphosphines by palladium-catalyzed annulation of 1-alkynylphosphine sulfides with 2-iodoanilines.
Org Lett. 2010 Apr 02; 12(7):1476-9.OL

Abstract

Palladium-catalyzed annulation of 1-alkynylphosphine sulfides with 2-iodoanilines followed by desulfidation affords 3-substituted 2-indolylphosphines. This annulation/desulfidation sequential protocol offers a conceptually new approach to bulky heteroarylphosphines.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Kondoh A
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
Yorimitsu H
No affiliation info available
Oshima K
No affiliation info available

MeSH

AlkynesAniline CompoundsCatalysisIndolesMolecular StructureOrganometallic CompoundsPalladiumPhosphinesStereoisomerismSulfides

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

20205465

Citation

Kondoh, Azusa, et al. "Synthesis of 2-indolylphosphines By Palladium-catalyzed Annulation of 1-alkynylphosphine Sulfides With 2-iodoanilines." Organic Letters, vol. 12, no. 7, 2010, pp. 1476-9.
Kondoh A, Yorimitsu H, Oshima K. Synthesis of 2-indolylphosphines by palladium-catalyzed annulation of 1-alkynylphosphine sulfides with 2-iodoanilines. Org Lett. 2010;12(7):1476-9.
Kondoh, A., Yorimitsu, H., & Oshima, K. (2010). Synthesis of 2-indolylphosphines by palladium-catalyzed annulation of 1-alkynylphosphine sulfides with 2-iodoanilines. Organic Letters, 12(7), 1476-9. https://doi.org/10.1021/ol1001544
Kondoh A, Yorimitsu H, Oshima K. Synthesis of 2-indolylphosphines By Palladium-catalyzed Annulation of 1-alkynylphosphine Sulfides With 2-iodoanilines. Org Lett. 2010 Apr 2;12(7):1476-9. PubMed PMID: 20205465.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Synthesis of 2-indolylphosphines by palladium-catalyzed annulation of 1-alkynylphosphine sulfides with 2-iodoanilines. AU - Kondoh,Azusa, AU - Yorimitsu,Hideki, AU - Oshima,Koichiro, PY - 2010/3/9/entrez PY - 2010/3/9/pubmed PY - 2010/6/25/medline SP - 1476 EP - 9 JF - Organic letters JO - Org Lett VL - 12 IS - 7 N2 - Palladium-catalyzed annulation of 1-alkynylphosphine sulfides with 2-iodoanilines followed by desulfidation affords 3-substituted 2-indolylphosphines. This annulation/desulfidation sequential protocol offers a conceptually new approach to bulky heteroarylphosphines. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/20205465/Synthesis_of_2_indolylphosphines_by_palladium_catalyzed_annulation_of_1_alkynylphosphine_sulfides_with_2_iodoanilines_ L2 - https://doi.org/10.1021/ol1001544 DB - PRIME DP - Unbound Medicine ER -